DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION

Poly(ethylene terephthalate) waste was degraded by glycolysis in order to obtain low molecular weight molecules for the batch removal of Cd(II), Cr(III), Cu(II), Ni(II), and Pb(II) from aqueous solution. The degradation product was characterized by IR, H¹NMR, DSC, and GPC, being identified as bis(2-...

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Autores principales: HERNÁNDEZ,M. A, ELIZONDO,P, SÁNCHEZ,M.G, PÉREZ,N.A, ELIZALDE,L.E, RIVAS,B.L
Lenguaje:English
Publicado: Sociedad Chilena de Química 2015
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400001
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spelling oai:scielo:S0717-970720150004000012016-02-23DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTIONHERNÁNDEZ,M. AELIZONDO,PSÁNCHEZ,M.GPÉREZ,N.AELIZALDE,L.ERIVAS,B.L adsorption metal ions PET degradation removal Poly(ethylene terephthalate) waste was degraded by glycolysis in order to obtain low molecular weight molecules for the batch removal of Cd(II), Cr(III), Cu(II), Ni(II), and Pb(II) from aqueous solution. The degradation product was characterized by IR, H¹NMR, DSC, and GPC, being identified as bis(2-hydroxy ethyl) terephthalate (BHET). The results show that metal absorption follows the order Pb(II)>Cd(II)>Ni(II)>Cu(II)>Cr(III). Degraded PET presented an affinity to remove over 75% of lead in solution at pH 4 and 5 and cadmium over 70% at pH 6. IR spectroscopy and DSC evidenced the presence of metal ions in the structure of the material.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.60 n.4 20152015-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400001en10.4067/S0717-97072015000400001
institution Scielo Chile
collection Scielo Chile
language English
topic adsorption
metal ions
PET degradation
removal
spellingShingle adsorption
metal ions
PET degradation
removal
HERNÁNDEZ,M. A
ELIZONDO,P
SÁNCHEZ,M.G
PÉREZ,N.A
ELIZALDE,L.E
RIVAS,B.L
DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
description Poly(ethylene terephthalate) waste was degraded by glycolysis in order to obtain low molecular weight molecules for the batch removal of Cd(II), Cr(III), Cu(II), Ni(II), and Pb(II) from aqueous solution. The degradation product was characterized by IR, H¹NMR, DSC, and GPC, being identified as bis(2-hydroxy ethyl) terephthalate (BHET). The results show that metal absorption follows the order Pb(II)>Cd(II)>Ni(II)>Cu(II)>Cr(III). Degraded PET presented an affinity to remove over 75% of lead in solution at pH 4 and 5 and cadmium over 70% at pH 6. IR spectroscopy and DSC evidenced the presence of metal ions in the structure of the material.
author HERNÁNDEZ,M. A
ELIZONDO,P
SÁNCHEZ,M.G
PÉREZ,N.A
ELIZALDE,L.E
RIVAS,B.L
author_facet HERNÁNDEZ,M. A
ELIZONDO,P
SÁNCHEZ,M.G
PÉREZ,N.A
ELIZALDE,L.E
RIVAS,B.L
author_sort HERNÁNDEZ,M. A
title DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
title_short DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
title_full DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
title_fullStr DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
title_full_unstemmed DEGRADED PET FOR THE REMOVAL OF METAL IONS FROM AQUEOUS SOLUTION
title_sort degraded pet for the removal of metal ions from aqueous solution
publisher Sociedad Chilena de Química
publishDate 2015
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400001
work_keys_str_mv AT hernandezma degradedpetfortheremovalofmetalionsfromaqueoussolution
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AT sanchezmg degradedpetfortheremovalofmetalionsfromaqueoussolution
AT perezna degradedpetfortheremovalofmetalionsfromaqueoussolution
AT elizaldele degradedpetfortheremovalofmetalionsfromaqueoussolution
AT rivasbl degradedpetfortheremovalofmetalionsfromaqueoussolution
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