SYNTHESIS OF 2,3-UNSATURATED O-GLYCOSIDES FROM OPTICALLY ACTIVE ALCOHOLS VIA FERRIER REARRANGEMENT: CONFIGURATIONAL STUDIES

SYNTHESIS OF 2,3-UNSATURATED O-GLYCOSIDES FROM OPTICALLY ACTIVE ALCOHOLS VIA FERRIER REARRANGEMENT: CONFIGURATIONAL STUDIES

4-[3-(aryl)-1,2,4-oxadiazol-5-yl] butanones 4a-e have been reduced to optically active 4-[3-(aryl)-1,2,4-oxadiazol-5-yl] butanols 5a-e with baker's yeast. We subjected the alcohols possessing (S)-configuration to Ferrier' rearrangement with tri-O-acetyl-D-glucal 6 which furnished new unsat...

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Autores principales: FILHO,JOÃO RUFINO FREITAS, FREITAS,JUCLEITON JOSÉ RUFINO DE, COTTIER,LOUIS, SINOU,DENIS, SRIVASTAVA,RAJENDRA MOHAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2015
Materias:
Configuration
Crystallographic data
baker's yeast
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400004
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