SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES

The macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n, were prepared from the respective polymer and PtCl2 in metal:polymer molar ratios 1:1 and 1:5. Pyrolisis of the macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n at 80...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	DÍAZ,CARLOS, VALENZUELA,MARÍA LUISA, BAEZ,RODRIGO, SEGOVIA,MARJORIE
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2015
Materias:	Nanoparticles Solid State Polymers Plasmon
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400016
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072015000400016
record_format	dspace
spelling	oai:scielo:S0717-970720150004000162016-02-23SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXESDÍAZ,CARLOSVALENZUELA,MARÍA LUISABAEZ,RODRIGOSEGOVIA,MARJORIE Nanoparticles Solid State Polymers Plasmon The macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n, were prepared from the respective polymer and PtCl2 in metal:polymer molar ratios 1:1 and 1:5. Pyrolisis of the macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n at 800 °C under air affords cubic nanostructured Pt in the pure phase. The morphology of the pyrolityc products depends on the molar metal:polymer ratio; i.e. a "cotton" 3D shape for the 1:1 ratio and a 'foamy" 3D shape for the 1:5 ratio. On the other hand, the particle size depends on the polymer nature, obtaining Pt nanoparticles as small as 6 nm for the chitosan precursors in both molar ratio.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.60 n.4 20152015-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400016en10.4067/S0717-97072015000400016
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Nanoparticles Solid State Polymers Plasmon
spellingShingle	Nanoparticles Solid State Polymers Plasmon DÍAZ,CARLOS VALENZUELA,MARÍA LUISA BAEZ,RODRIGO SEGOVIA,MARJORIE SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
description	The macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n, were prepared from the respective polymer and PtCl2 in metal:polymer molar ratios 1:1 and 1:5. Pyrolisis of the macromolecular complexes Chitosan●(PtCl2)n and PSP-co-4-PVP●(PtCl2)n at 800 °C under air affords cubic nanostructured Pt in the pure phase. The morphology of the pyrolityc products depends on the molar metal:polymer ratio; i.e. a "cotton" 3D shape for the 1:1 ratio and a 'foamy" 3D shape for the 1:5 ratio. On the other hand, the particle size depends on the polymer nature, obtaining Pt nanoparticles as small as 6 nm for the chitosan precursors in both molar ratio.
author	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA BAEZ,RODRIGO SEGOVIA,MARJORIE
author_facet	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA BAEZ,RODRIGO SEGOVIA,MARJORIE
author_sort	DÍAZ,CARLOS
title	SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
title_short	SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
title_full	SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
title_fullStr	SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
title_full_unstemmed	SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES
title_sort	solid state morphology and size tuning of nanostructured platinum using macromolecular complexes
publisher	Sociedad Chilena de Química
publishDate	2015
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000400016
work_keys_str_mv	AT diazcarlos solidstatemorphologyandsizetuningofnanostructuredplatinumusingmacromolecularcomplexes AT valenzuelamarialuisa solidstatemorphologyandsizetuningofnanostructuredplatinumusingmacromolecularcomplexes AT baezrodrigo solidstatemorphologyandsizetuningofnanostructuredplatinumusingmacromolecularcomplexes AT segoviamarjorie solidstatemorphologyandsizetuningofnanostructuredplatinumusingmacromolecularcomplexes
_version_	1718445544562491392

SOLID STATE MORPHOLOGY AND SIZE TUNING OF NANOSTRUCTURED PLATINUM USING MACROMOLECULAR COMPLEXES

Ejemplares similares