MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING

Gold nanoparticles (AuNPs) were deposited by DC-magnetron sputtering onto molybdenum trioxide (MoO3) thin films grown by Photochemical Metal-Organic Deposition (PMOD) on Si(100) and borosilicate glass substrates. The chemical, optical and morphology properties of the films were studied by UV/ Vis Sp...

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Autores principales: CASTILLO,C, BUONO-CORE,G, MANZUR,C, YUTRONIC,N, SIERPE,R, CABELLO,G, CHORNIK,B
Lenguaje:English
Publicado: Sociedad Chilena de Química 2016
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000100014
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spelling oai:scielo:S0717-970720160001000142016-09-14MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERINGCASTILLO,CBUONO-CORE,GMANZUR,CYUTRONIC,NSIERPE,RCABELLO,GCHORNIK,B A. oxides A. thin films A. nanostructures B. sputtering C. x-ray diffraction C. photoelectron spectroscopy Gold nanoparticles (AuNPs) were deposited by DC-magnetron sputtering onto molybdenum trioxide (MoO3) thin films grown by Photochemical Metal-Organic Deposition (PMOD) on Si(100) and borosilicate glass substrates. The chemical, optical and morphology properties of the films were studied by UV/ Vis Spectroscopy, Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD). SEM revealed that AuNPs formed after 5 s of sputtering. AuNPs are spherical and have both an average diameter of 18 nm and a relatively narrow size distribution. As the deposition time increases, larger structures are formed by an aggregation of AuNPs. XPS studies of the AuNP/MoO3 films on Si(100) showed the presence of Mo(VI) and Mo(V), which indicated that the films were primarily non-stoichiometric molybdenum oxides. The occurrence of oxygen vacancies in the substrate play an important role to stabilize the AuNPs.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.1 20162016-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000100014en10.4067/S0717-97072016000100014
institution Scielo Chile
collection Scielo Chile
language English
topic A. oxides
A. thin films
A. nanostructures
B. sputtering
C. x-ray diffraction
C. photoelectron spectroscopy
spellingShingle A. oxides
A. thin films
A. nanostructures
B. sputtering
C. x-ray diffraction
C. photoelectron spectroscopy
CASTILLO,C
BUONO-CORE,G
MANZUR,C
YUTRONIC,N
SIERPE,R
CABELLO,G
CHORNIK,B
MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
description Gold nanoparticles (AuNPs) were deposited by DC-magnetron sputtering onto molybdenum trioxide (MoO3) thin films grown by Photochemical Metal-Organic Deposition (PMOD) on Si(100) and borosilicate glass substrates. The chemical, optical and morphology properties of the films were studied by UV/ Vis Spectroscopy, Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD). SEM revealed that AuNPs formed after 5 s of sputtering. AuNPs are spherical and have both an average diameter of 18 nm and a relatively narrow size distribution. As the deposition time increases, larger structures are formed by an aggregation of AuNPs. XPS studies of the AuNP/MoO3 films on Si(100) showed the presence of Mo(VI) and Mo(V), which indicated that the films were primarily non-stoichiometric molybdenum oxides. The occurrence of oxygen vacancies in the substrate play an important role to stabilize the AuNPs.
author CASTILLO,C
BUONO-CORE,G
MANZUR,C
YUTRONIC,N
SIERPE,R
CABELLO,G
CHORNIK,B
author_facet CASTILLO,C
BUONO-CORE,G
MANZUR,C
YUTRONIC,N
SIERPE,R
CABELLO,G
CHORNIK,B
author_sort CASTILLO,C
title MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
title_short MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
title_full MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
title_fullStr MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
title_full_unstemmed MOLYBDENUM TRIOXIDE THIN FILMS DOPED WITH GOLD NANOPARTICLES GROWN BY A SEQUENTIAL METHODOLOGY: PHOTOCHEMICAL METAL-ORGANIC DEPOSITION (PMOD) AND DC-MAGNETRON SPUTTERING
title_sort molybdenum trioxide thin films doped with gold nanoparticles grown by a sequential methodology: photochemical metal-organic deposition (pmod) and dc-magnetron sputtering
publisher Sociedad Chilena de Química
publishDate 2016
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000100014
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AT manzurc molybdenumtrioxidethinfilmsdopedwithgoldnanoparticlesgrownbyasequentialmethodologyphotochemicalmetalorganicdepositionpmodanddcmagnetronsputtering
AT yutronicn molybdenumtrioxidethinfilmsdopedwithgoldnanoparticlesgrownbyasequentialmethodologyphotochemicalmetalorganicdepositionpmodanddcmagnetronsputtering
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AT cabellog molybdenumtrioxidethinfilmsdopedwithgoldnanoparticlesgrownbyasequentialmethodologyphotochemicalmetalorganicdepositionpmodanddcmagnetronsputtering
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