VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS

Major objective of this study was to appraise the variation of antioxidant activity, total phenols, total flavonoids and individual phenolic acids among fruit peels from five species of Citrus namely C. sinensis 'Valancia' (Mausami), C. sinensis 'Maltaise Sanguine' (Red blood), C...

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Autores principales: ZAHOOR,SADAF, ANWAR,FAROOQ, MEHMOOD,TAHIR, SULTANA,BUSHRA, QADIR,RAHMAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2016
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200007
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spelling oai:scielo:S0717-970720160002000072016-09-14VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTSZAHOOR,SADAFANWAR,FAROOQMEHMOOD,TAHIRSULTANA,BUSHRAQADIR,RAHMAN Citrus Peel extracts Extraction solvents Antioxidant activity Total phenolics and Flavonoids Phenolic acids HPLC Major objective of this study was to appraise the variation of antioxidant activity, total phenols, total flavonoids and individual phenolic acids among fruit peels from five species of Citrus namely C. sinensis 'Valancia' (Mausami), C. sinensis 'Maltaise Sanguine' (Red blood), C. reticulata (Kinnow), C. reticulata Blanco 'Merisol' (Fruiter), and C. paradisi 'Macfadyen' (Grapefruit) as function of extraction solvents. The extract yield from the fruit peels of the selected Citrus species by using four solvents varied significantly (p<0.05) 17.56-49.13 g/100g in relation to the extraction media and type of peel. The highest extraction yield was obtained with 100% methanol from Red blood (C. sinensis 'Maltaise Sanguine') peel while the least with 100% ethanol from Fruiter (C. reticulata Blanco 'Merisol') peel. The total phenolic contents (TPC), total flavonoid contents (TFC), DPPH radical scavenging activity (IC50) and reducing power [FRAP (EC50)] for peel extracts ranged from 13.69 to 66.10 GAE mg/g of dry weight (DW), 9.34 to 28.99 CE mg/g DW, 0.33 to 2.32 mg/mL and 2.05 to 6.76 mg/mL, respectively. According to HPLC analysis of peel extracts, gallic acid and protocatechuic acid with contribution 11.96-96.08 and 109.18-578.59mg/kg of extract, respectively, were detected to be the main phenolic acids among others. Total amount of individual phenolic acids (TPAs) in the tested peels varied over 18.37 to 1015.99 mg/kg of extract. The highest amount of TPAs was extracted in Red blood (C. sinensis 'Maltaise Sanguine') with 80% methanol while the least in Grapefruit (C. paradisi 'Macfadyen') with 100% methanol. It can be concluded from the present data that both the species and extraction solvents have notable effect on the antioxidant attributes and phenolics of citrus peels. Overall, the results of this study showed that extracts from peel of Red blood (C. sinensis 'Maltaise Sanguine'), among others, possessed superior antioxidant activity and greater amount of phenolic acids.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.2 20162016-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200007en10.4067/S0717-97072016000200007
institution Scielo Chile
collection Scielo Chile
language English
topic Citrus Peel extracts
Extraction solvents
Antioxidant activity
Total phenolics and Flavonoids
Phenolic acids
HPLC
spellingShingle Citrus Peel extracts
Extraction solvents
Antioxidant activity
Total phenolics and Flavonoids
Phenolic acids
HPLC
ZAHOOR,SADAF
ANWAR,FAROOQ
MEHMOOD,TAHIR
SULTANA,BUSHRA
QADIR,RAHMAN
VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
description Major objective of this study was to appraise the variation of antioxidant activity, total phenols, total flavonoids and individual phenolic acids among fruit peels from five species of Citrus namely C. sinensis 'Valancia' (Mausami), C. sinensis 'Maltaise Sanguine' (Red blood), C. reticulata (Kinnow), C. reticulata Blanco 'Merisol' (Fruiter), and C. paradisi 'Macfadyen' (Grapefruit) as function of extraction solvents. The extract yield from the fruit peels of the selected Citrus species by using four solvents varied significantly (p<0.05) 17.56-49.13 g/100g in relation to the extraction media and type of peel. The highest extraction yield was obtained with 100% methanol from Red blood (C. sinensis 'Maltaise Sanguine') peel while the least with 100% ethanol from Fruiter (C. reticulata Blanco 'Merisol') peel. The total phenolic contents (TPC), total flavonoid contents (TFC), DPPH radical scavenging activity (IC50) and reducing power [FRAP (EC50)] for peel extracts ranged from 13.69 to 66.10 GAE mg/g of dry weight (DW), 9.34 to 28.99 CE mg/g DW, 0.33 to 2.32 mg/mL and 2.05 to 6.76 mg/mL, respectively. According to HPLC analysis of peel extracts, gallic acid and protocatechuic acid with contribution 11.96-96.08 and 109.18-578.59mg/kg of extract, respectively, were detected to be the main phenolic acids among others. Total amount of individual phenolic acids (TPAs) in the tested peels varied over 18.37 to 1015.99 mg/kg of extract. The highest amount of TPAs was extracted in Red blood (C. sinensis 'Maltaise Sanguine') with 80% methanol while the least in Grapefruit (C. paradisi 'Macfadyen') with 100% methanol. It can be concluded from the present data that both the species and extraction solvents have notable effect on the antioxidant attributes and phenolics of citrus peels. Overall, the results of this study showed that extracts from peel of Red blood (C. sinensis 'Maltaise Sanguine'), among others, possessed superior antioxidant activity and greater amount of phenolic acids.
author ZAHOOR,SADAF
ANWAR,FAROOQ
MEHMOOD,TAHIR
SULTANA,BUSHRA
QADIR,RAHMAN
author_facet ZAHOOR,SADAF
ANWAR,FAROOQ
MEHMOOD,TAHIR
SULTANA,BUSHRA
QADIR,RAHMAN
author_sort ZAHOOR,SADAF
title VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
title_short VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
title_full VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
title_fullStr VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
title_full_unstemmed VARIATION IN ANTIOXIDANT ATTRIBUTES AND INDIVIDUAL PHENOLICS OF CITRUS FRUIT PEELS IN RELATION TO DIFFERENT SPECIES AND EXTRACTION SOLVENTS
title_sort variation in antioxidant attributes and individual phenolics of citrus fruit peels in relation to different species and extraction solvents
publisher Sociedad Chilena de Química
publishDate 2016
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200007
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