SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES

The organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6...

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Autores principales:	DADRASS,ALIREZA, RAHCHAMANI,HOJJATOLLAH
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Materias:	Organophousphorus complexes Phosphorus complexes Theoretical studies of dimeric compounds crystal structure triphenyl complexes
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200023
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spelling	oai:scielo:S0717-970720160002000232016-09-14SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDESDADRASS,ALIREZARAHCHAMANI,HOJJATOLLAH Organophousphorus complexes Phosphorus complexes Theoretical studies of dimeric compounds crystal structure triphenyl complexes The organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6 have been determined by means of the X-ray diffraction. Both complexes were crystallized in the monoclinic space groups P2(1)/c, and have very similar bond lengths, angles pattern and same substituted triphenylphosphine ligand. Single crystal X-ray analysis of title structures reveal the presence of a centrosymmeteric dimeric structure containing the ligand and mercury halides.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.2 20162016-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200023en10.4067/S0717-97072016000200023
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Organophousphorus complexes Phosphorus complexes Theoretical studies of dimeric compounds crystal structure triphenyl complexes
spellingShingle	Organophousphorus complexes Phosphorus complexes Theoretical studies of dimeric compounds crystal structure triphenyl complexes DADRASS,ALIREZA RAHCHAMANI,HOJJATOLLAH SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
description	The organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6 have been determined by means of the X-ray diffraction. Both complexes were crystallized in the monoclinic space groups P2(1)/c, and have very similar bond lengths, angles pattern and same substituted triphenylphosphine ligand. Single crystal X-ray analysis of title structures reveal the presence of a centrosymmeteric dimeric structure containing the ligand and mercury halides.
author	DADRASS,ALIREZA RAHCHAMANI,HOJJATOLLAH
author_facet	DADRASS,ALIREZA RAHCHAMANI,HOJJATOLLAH
author_sort	DADRASS,ALIREZA
title	SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
title_short	SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
title_full	SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
title_fullStr	SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
title_full_unstemmed	SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
title_sort	synthesis of organophosphorus complexes and structural charaterization of two dimeric triphenylphosphinne complexes of mercury(ii) ions from dimeric complexes of [4-methylbenzoylmethylenetri-p-tolylphosphine mercury(ii) halides
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200023
work_keys_str_mv	AT dadrassalireza synthesisoforganophosphoruscomplexesandstructuralcharaterizationoftwodimerictriphenylphosphinnecomplexesofmercuryiiionsfromdimericcomplexesof4methylbenzoylmethylenetriptolylphosphinemercuryiihalides AT rahchamanihojjatollah synthesisoforganophosphoruscomplexesandstructuralcharaterizationoftwodimerictriphenylphosphinnecomplexesofmercuryiiionsfromdimericcomplexesof4methylbenzoylmethylenetriptolylphosphinemercuryiihalides
_version_	1718445553403035648

SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES

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