A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES

A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES

A novel acentric char sulfate compound, [Cd(S2O7)(4,4,-bipyridine)(H2O)2]n (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction method. Compound 1 is characterized by a three-dimensional (3-D) inorganic-organic hybrid framework structure. Solid-state photolu...

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Autores principales: HE,DE-YONG, CHEN,WEN-TONG
Lenguaje:English
Publicado: Sociedad Chilena de Química 2016
Materias:
char sulfate
framework
hybrid
photoluminescence
NLO
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200032
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spelling oai:scielo:S0717-970720160002000322016-09-14A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIESHE,DE-YONGCHEN,WEN-TONG char sulfate framework hybrid photoluminescence NLO A novel acentric char sulfate compound, [Cd(S2O7)(4,4,-bipyridine)(H2O)2]n (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction method. Compound 1 is characterized by a three-dimensional (3-D) inorganic-organic hybrid framework structure. Solid-state photoluminescent spectra indicate that compound 1 displays a strong violet emission. The second-order nonlinear optical measurements reveal that compound 1 has modest powder SHG efficiency of about 0.02 times than that produced by a potassium dihydrogen phosphate (KDP) powder. Optical absorption spectrum discovers that the presence of an optical gap of 3.41 eV, suggesting that compound 1 is a wide bandgap semiconductor.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.2 20162016-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200032en10.4067/S0717-97072016000200032
institution Scielo Chile
collection Scielo Chile
language English
topic char sulfate
framework
hybrid
photoluminescence
NLO
spellingShingle char sulfate
framework
hybrid
photoluminescence
NLO
HE,DE-YONG
CHEN,WEN-TONG
A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
description A novel acentric char sulfate compound, [Cd(S2O7)(4,4,-bipyridine)(H2O)2]n (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction method. Compound 1 is characterized by a three-dimensional (3-D) inorganic-organic hybrid framework structure. Solid-state photoluminescent spectra indicate that compound 1 displays a strong violet emission. The second-order nonlinear optical measurements reveal that compound 1 has modest powder SHG efficiency of about 0.02 times than that produced by a potassium dihydrogen phosphate (KDP) powder. Optical absorption spectrum discovers that the presence of an optical gap of 3.41 eV, suggesting that compound 1 is a wide bandgap semiconductor.
author HE,DE-YONG
CHEN,WEN-TONG
author_facet HE,DE-YONG
CHEN,WEN-TONG
author_sort HE,DE-YONG
title A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
title_short A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
title_full A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
title_fullStr A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
title_full_unstemmed A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES
title_sort novel acentric char sulfate inorganic-organic hybrid framework: photoluminescent, nlo and semiconductor properties
publisher Sociedad Chilena de Química
publishDate 2016
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000200032
work_keys_str_mv AT hedeyong anovelacentriccharsulfateinorganicorganichybridframeworkphotoluminescentnloandsemiconductorproperties
AT chenwentong anovelacentriccharsulfateinorganicorganichybridframeworkphotoluminescentnloandsemiconductorproperties
AT hedeyong novelacentriccharsulfateinorganicorganichybridframeworkphotoluminescentnloandsemiconductorproperties
AT chenwentong novelacentriccharsulfateinorganicorganichybridframeworkphotoluminescentnloandsemiconductorproperties
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