FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE

The title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The...

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Autores principales: SHIRVAN,SADIF A, KHAZALI,FEREYDOON, DEZFULI,SARA HAYDARI, BORSALANI,ALI
Lenguaje:English
Publicado: Sociedad Chilena de Química 2016
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300008
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spelling oai:scielo:S0717-970720160003000082017-06-14FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNESHIRVAN,SADIF AKHAZALI,FEREYDOONDEZFULI,SARA HAYDARIBORSALANI,ALIThe title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The mid-point of the N-N bond (1.412(13) Å) lies on an inversion center. The molecular skeleton is approximately planar. In the crystal packing of this complex, neighboring molecules are linked to each other by H...H intermolecular interactions to form 2D sheets.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.3 20162016-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300008en10.4067/S0717-97072016000300008
institution Scielo Chile
collection Scielo Chile
language English
description The title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The mid-point of the N-N bond (1.412(13) Å) lies on an inversion center. The molecular skeleton is approximately planar. In the crystal packing of this complex, neighboring molecules are linked to each other by H...H intermolecular interactions to form 2D sheets.
author SHIRVAN,SADIF A
KHAZALI,FEREYDOON
DEZFULI,SARA HAYDARI
BORSALANI,ALI
spellingShingle SHIRVAN,SADIF A
KHAZALI,FEREYDOON
DEZFULI,SARA HAYDARI
BORSALANI,ALI
FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
author_facet SHIRVAN,SADIF A
KHAZALI,FEREYDOON
DEZFULI,SARA HAYDARI
BORSALANI,ALI
author_sort SHIRVAN,SADIF A
title FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
title_short FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
title_full FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
title_fullStr FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
title_full_unstemmed FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
title_sort formation of 2d sheets through h…h interaction in the crystal packing of 1,2-bis(3-bromobenzylidene)hydrazne
publisher Sociedad Chilena de Química
publishDate 2016
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300008
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AT khazalifereydoon formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne
AT dezfulisarahaydari formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne
AT borsalaniali formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne
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