FORMATION OF 2D SHEETS THROUGH H H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE
The title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The...
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Sociedad Chilena de Química
2016
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oai:scielo:S0717-970720160003000082017-06-14FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNESHIRVAN,SADIF AKHAZALI,FEREYDOONDEZFULI,SARA HAYDARIBORSALANI,ALIThe title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The mid-point of the N-N bond (1.412(13) Å) lies on an inversion center. The molecular skeleton is approximately planar. In the crystal packing of this complex, neighboring molecules are linked to each other by H...H intermolecular interactions to form 2D sheets.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.3 20162016-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300008en10.4067/S0717-97072016000300008 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
description |
The title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P2(1)/c monoclinic space group. The mid-point of the N-N bond (1.412(13) Å) lies on an inversion center. The molecular skeleton is approximately planar. In the crystal packing of this complex, neighboring molecules are linked to each other by H...H intermolecular interactions to form 2D sheets. |
author |
SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI |
spellingShingle |
SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI FORMATION OF 2D SHEETS THROUGH H H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
author_facet |
SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI |
author_sort |
SHIRVAN,SADIF A |
title |
FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
title_short |
FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
title_full |
FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
title_fullStr |
FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
title_full_unstemmed |
FORMATION OF 2D SHEETS THROUGH H
H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3-BROMOBENZYLIDENE)HYDRAZNE |
title_sort |
formation of 2d sheets through h
h interaction in the crystal packing of 1,2-bis(3-bromobenzylidene)hydrazne |
publisher |
Sociedad Chilena de Química |
publishDate |
2016 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300008 |
work_keys_str_mv |
AT shirvansadifa formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne AT khazalifereydoon formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne AT dezfulisarahaydari formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne AT borsalaniali formationof2dsheetsthroughhhinteractioninthecrystalpackingof12bis3bromobenzylidenehydrazne |
_version_ |
1714200895924731904 |