THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE
The inhibition effect of 2,2'- (((thiobis (4,1 phenylene)) bis(azanylylidene)) bis(methanylyidene)) bis(4-methoxyphenol) (BIS-IMIN) on the corrosion behavior of 304-stainless steel (SS) in 0.5 M HCl solution was studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polariz...
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Sociedad Chilena de Química
2016
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oai:scielo:S0717-970720160003000122017-06-14THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASEBAKIRHAN,N. KASAN,ACOLAK,NSANLI,S Corrosion inhibitors Stainless steel potentiodynamic polarization Electrochemical impedance spectroscopy The inhibition effect of 2,2'- (((thiobis (4,1 phenylene)) bis(azanylylidene)) bis(methanylyidene)) bis(4-methoxyphenol) (BIS-IMIN) on the corrosion behavior of 304-stainless steel (SS) in 0.5 M HCl solution was studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. SEM, FT-IR, ¹H-NMR, 13C-NMR methods used for characterization of BIS-IMIN. Potentiodynamic polarization curves indicated that BIS-IMIN act as mixed type inhibitor. The adsorption of the inhibitor was more suited with the Langmuir adsorption isotherm and kinetic parameters Kads, ΔGads Ea , ΔHads, ΔSads were determined at room temperature. The results showed that BIS-IMIN performed well inhibiting effect for the corrosion of the SS.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.3 20162016-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300012en10.4067/S0717-97072016000300012 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Corrosion inhibitors Stainless steel potentiodynamic polarization Electrochemical impedance spectroscopy |
spellingShingle |
Corrosion inhibitors Stainless steel potentiodynamic polarization Electrochemical impedance spectroscopy BAKIRHAN,N. K ASAN,A COLAK,N SANLI,S THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
description |
The inhibition effect of 2,2'- (((thiobis (4,1 phenylene)) bis(azanylylidene)) bis(methanylyidene)) bis(4-methoxyphenol) (BIS-IMIN) on the corrosion behavior of 304-stainless steel (SS) in 0.5 M HCl solution was studied by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. SEM, FT-IR, ¹H-NMR, 13C-NMR methods used for characterization of BIS-IMIN. Potentiodynamic polarization curves indicated that BIS-IMIN act as mixed type inhibitor. The adsorption of the inhibitor was more suited with the Langmuir adsorption isotherm and kinetic parameters Kads, ΔGads Ea , ΔHads, ΔSads were determined at room temperature. The results showed that BIS-IMIN performed well inhibiting effect for the corrosion of the SS. |
author |
BAKIRHAN,N. K ASAN,A COLAK,N SANLI,S |
author_facet |
BAKIRHAN,N. K ASAN,A COLAK,N SANLI,S |
author_sort |
BAKIRHAN,N. K |
title |
THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
title_short |
THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
title_full |
THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
title_fullStr |
THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
title_full_unstemmed |
THE INHIBITION OF STEEL CORROSION IN ACIDIC SOLUTIONS BY A NEW SCHIFF BASE |
title_sort |
inhibition of steel corrosion in acidic solutions by a new schiff base |
publisher |
Sociedad Chilena de Química |
publishDate |
2016 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300012 |
work_keys_str_mv |
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