SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES

In present investigation, N-substituted propylaminepolyaniline (N-PAPANI) was prepared by reaction of dimethylsulfoxide solution of polyaniline (emeraldine) base with sodium hydride, then reacted with 3-chloropropylaminehydrochloride. The N-PAPANI was characterized using reflectance Fourier transfor...

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Autores principales:	TARASSI,M.A, ZADEHNAZARI,A
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Materias:	N-propylaminepolyaniline direct oxidation Friedel-Craft synthesis
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300020
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spelling	oai:scielo:S0717-970720160003000202017-06-14SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIESTARASSI,M.AZADEHNAZARI,A N-propylaminepolyaniline direct oxidation Friedel-Craft synthesis In present investigation, N-substituted propylaminepolyaniline (N-PAPANI) was prepared by reaction of dimethylsulfoxide solution of polyaniline (emeraldine) base with sodium hydride, then reacted with 3-chloropropylaminehydrochloride. The N-PAPANI was characterized using reflectance Fourier transformation infrared (FTIR), cyclic voltammetry, UV-vis spectroscopy and chemical analysis. Polyaniline (PANI) was also subjected to a reaction with 3-chloropropylaminehydrochloride and ferric chloride in acetonitrile as solvent under refluxing temperature (85-90 °C) (Friedel-Craft synthetic method) to produce ring substituted functionalized PAPANI. Characterization of PAPANI was carried out using various aforementioned techniques. PANI and N-PAPANI polymers exhibited strong UV-vis absorption maxima at 273-294 nm in solution. Cyclic voltammograms of the polymers on an indium-tin oxide (ITO)-coated glass substrate exhibited one pair of reversible redox couples at half-wave oxidation potentials (E1/2) around 0.84-0.86 V and 0.88 V, respectively, versus Ag/AgCl in an acetonitrile solution. The obtained polymers showed good solubility in common organic solvents such as tetrahydrofuran and chloroform compared with emeraldine which is difficult to process due to lack of solubility. Furthermore, these polymers are air stable.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.3 20162016-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300020en10.4067/S0717-97072016000300020
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	N-propylaminepolyaniline direct oxidation Friedel-Craft synthesis
spellingShingle	N-propylaminepolyaniline direct oxidation Friedel-Craft synthesis TARASSI,M.A ZADEHNAZARI,A SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
description	In present investigation, N-substituted propylaminepolyaniline (N-PAPANI) was prepared by reaction of dimethylsulfoxide solution of polyaniline (emeraldine) base with sodium hydride, then reacted with 3-chloropropylaminehydrochloride. The N-PAPANI was characterized using reflectance Fourier transformation infrared (FTIR), cyclic voltammetry, UV-vis spectroscopy and chemical analysis. Polyaniline (PANI) was also subjected to a reaction with 3-chloropropylaminehydrochloride and ferric chloride in acetonitrile as solvent under refluxing temperature (85-90 °C) (Friedel-Craft synthetic method) to produce ring substituted functionalized PAPANI. Characterization of PAPANI was carried out using various aforementioned techniques. PANI and N-PAPANI polymers exhibited strong UV-vis absorption maxima at 273-294 nm in solution. Cyclic voltammograms of the polymers on an indium-tin oxide (ITO)-coated glass substrate exhibited one pair of reversible redox couples at half-wave oxidation potentials (E1/2) around 0.84-0.86 V and 0.88 V, respectively, versus Ag/AgCl in an acetonitrile solution. The obtained polymers showed good solubility in common organic solvents such as tetrahydrofuran and chloroform compared with emeraldine which is difficult to process due to lack of solubility. Furthermore, these polymers are air stable.
author	TARASSI,M.A ZADEHNAZARI,A
author_facet	TARASSI,M.A ZADEHNAZARI,A
author_sort	TARASSI,M.A
title	SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
title_short	SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
title_full	SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
title_fullStr	SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
title_full_unstemmed	SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES
title_sort	synthesis of functionalized propylaminepolyanilines and investigation of their properties
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000300020
work_keys_str_mv	AT tarassima synthesisoffunctionalizedpropylaminepolyanilinesandinvestigationoftheirproperties AT zadehnazaria synthesisoffunctionalizedpropylaminepolyanilinesandinvestigationoftheirproperties
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SYNTHESIS OF FUNCTIONALIZED PROPYLAMINEPOLYANILINES AND INVESTIGATION OF THEIR PROPERTIES

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