SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST

The conversion of quinoline over ReS2 supported on y-Al2O3, SiO2, ZrO2 and TiO2 catalysts in a batch reactor at 300ºC and 5 MPa of hydrogen pressure was studied. The catalysts were prepared by wet impregnation with a loading of 1.5 atoms of Re per nm² of support. The catalysts were characterized by...

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Autores principales:	BASSM,R, VILLARROEL,M, GIL-LLAMBIAS,F J, BAEZA,P, GARCÍA-FIERRO,J. L, MARTÍNEZ,N, OLIVERA,P, LEIVA,K, ESCALONA,N
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Materias:	Hydrodenitrogenation ReS2 quinoline supports
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400004
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spelling	oai:scielo:S0717-970720160004000042017-01-16SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYSTBASSM,RVILLARROEL,MGIL-LLAMBIAS,F JBAEZA,PGARCÍA-FIERRO,J. LMARTÍNEZ,NOLIVERA,PLEIVA,KESCALONA,N Hydrodenitrogenation ReS2 quinoline supports The conversion of quinoline over ReS2 supported on y-Al2O3, SiO2, ZrO2 and TiO2 catalysts in a batch reactor at 300ºC and 5 MPa of hydrogen pressure was studied. The catalysts were prepared by wet impregnation with a loading of 1.5 atoms of Re per nm² of support. The catalysts were characterized by N2 adsorption, X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRD). The Re(x)/supports catalysts displayed high activities for the conversion of quinoline, although negligible formation of N-free compounds (hydrodenitrogenation) were observed. The intrinsic activities of ReS2 were modified by the support decreased in the order: Re/TiO2 > Re/ZrO2 > Re/SiO2 > Re/y-Al2O3. The highest activity displayed by the Re/TiO2 catalyst was correlated with the Re dispersion and formation of ReS2 species. Meanwhile, the lower conversion of quinoline over the Re/ZrO2, Re/SiO2 and Re/y-Al2O3 catalysts was related to the combined effect of the textural properties of catalysts and the formation of ReS species on the supports.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400004en10.4067/S0717-97072016000400004
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Hydrodenitrogenation ReS2 quinoline supports
spellingShingle	Hydrodenitrogenation ReS2 quinoline supports BASSM,R VILLARROEL,M GIL-LLAMBIAS,F J BAEZA,P GARCÍA-FIERRO,J. L MARTÍNEZ,N OLIVERA,P LEIVA,K ESCALONA,N SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
description	The conversion of quinoline over ReS2 supported on y-Al2O3, SiO2, ZrO2 and TiO2 catalysts in a batch reactor at 300ºC and 5 MPa of hydrogen pressure was studied. The catalysts were prepared by wet impregnation with a loading of 1.5 atoms of Re per nm² of support. The catalysts were characterized by N2 adsorption, X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRD). The Re(x)/supports catalysts displayed high activities for the conversion of quinoline, although negligible formation of N-free compounds (hydrodenitrogenation) were observed. The intrinsic activities of ReS2 were modified by the support decreased in the order: Re/TiO2 > Re/ZrO2 > Re/SiO2 > Re/y-Al2O3. The highest activity displayed by the Re/TiO2 catalyst was correlated with the Re dispersion and formation of ReS2 species. Meanwhile, the lower conversion of quinoline over the Re/ZrO2, Re/SiO2 and Re/y-Al2O3 catalysts was related to the combined effect of the textural properties of catalysts and the formation of ReS species on the supports.
author	BASSM,R VILLARROEL,M GIL-LLAMBIAS,F J BAEZA,P GARCÍA-FIERRO,J. L MARTÍNEZ,N OLIVERA,P LEIVA,K ESCALONA,N
author_facet	BASSM,R VILLARROEL,M GIL-LLAMBIAS,F J BAEZA,P GARCÍA-FIERRO,J. L MARTÍNEZ,N OLIVERA,P LEIVA,K ESCALONA,N
author_sort	BASSM,R
title	SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
title_short	SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
title_full	SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
title_fullStr	SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
title_full_unstemmed	SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST
title_sort	support effect on conversion of quinoline over res2 catalyst
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400004
work_keys_str_mv	AT bassmr supporteffectonconversionofquinolineoverres2catalyst AT villarroelm supporteffectonconversionofquinolineoverres2catalyst AT gilllambiasfj supporteffectonconversionofquinolineoverres2catalyst AT baezap supporteffectonconversionofquinolineoverres2catalyst AT garciafierrojl supporteffectonconversionofquinolineoverres2catalyst AT martinezn supporteffectonconversionofquinolineoverres2catalyst AT oliverap supporteffectonconversionofquinolineoverres2catalyst AT leivak supporteffectonconversionofquinolineoverres2catalyst AT escalonan supporteffectonconversionofquinolineoverres2catalyst
_version_	1714200900259545088

SUPPORT EFFECT ON CONVERSION OF QUINOLINE OVER ReS2 CATALYST

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