STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE
The objective of this study was to evaluate the tannin extraction potential taken from the bark of Acacia dealbata. This tannins were extracted with water at 90°C. An extraction yield of 17.2% solids with a Stiasny number of 82% was obtained from the bark extract of Acacia dealbata. The structure wa...
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Sociedad Chilena de Química
2016
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oai:scielo:S0717-970720160004000072017-01-16STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDELISPERGUER,JUSTOSARAVIA,YANINAVERGARA,EMILIO Tannins Acacia dealbata bark Structure of tannins Thermal behavior The objective of this study was to evaluate the tannin extraction potential taken from the bark of Acacia dealbata. This tannins were extracted with water at 90°C. An extraction yield of 17.2% solids with a Stiasny number of 82% was obtained from the bark extract of Acacia dealbata. The structure was studied by Fourier transform infrared spectroscopy (FTIR). The thermal behavior of tannins was studied by DSC and a glass-transition temperature (Tg) of 116,77°C was determined. The thermal stability of tannins was studied by TGA. At 196.91°C the decomposition is 3.7% and the maximum of the weight loss rate (DTG) of the degradation was 257.77°C. The curing with formaldehyde showed an exotherm reaction in the range of 100-120°C, which is similar to tannins of other species.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400007en10.4067/S0717-97072016000400007 |
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Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
Tannins Acacia dealbata bark Structure of tannins Thermal behavior |
spellingShingle |
Tannins Acacia dealbata bark Structure of tannins Thermal behavior LISPERGUER,JUSTO SARAVIA,YANINA VERGARA,EMILIO STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
description |
The objective of this study was to evaluate the tannin extraction potential taken from the bark of Acacia dealbata. This tannins were extracted with water at 90°C. An extraction yield of 17.2% solids with a Stiasny number of 82% was obtained from the bark extract of Acacia dealbata. The structure was studied by Fourier transform infrared spectroscopy (FTIR). The thermal behavior of tannins was studied by DSC and a glass-transition temperature (Tg) of 116,77°C was determined. The thermal stability of tannins was studied by TGA. At 196.91°C the decomposition is 3.7% and the maximum of the weight loss rate (DTG) of the degradation was 257.77°C. The curing with formaldehyde showed an exotherm reaction in the range of 100-120°C, which is similar to tannins of other species. |
author |
LISPERGUER,JUSTO SARAVIA,YANINA VERGARA,EMILIO |
author_facet |
LISPERGUER,JUSTO SARAVIA,YANINA VERGARA,EMILIO |
author_sort |
LISPERGUER,JUSTO |
title |
STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
title_short |
STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
title_full |
STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
title_fullStr |
STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
title_full_unstemmed |
STRUCTURE AND THERMAL BEHAVIOR OF TANNINS FROM Acacia dealbata BARK AND THEIR REACTIVITY TOWARD FORMALDEHYDE |
title_sort |
structure and thermal behavior of tannins from acacia dealbata bark and their reactivity toward formaldehyde |
publisher |
Sociedad Chilena de Química |
publishDate |
2016 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400007 |
work_keys_str_mv |
AT lisperguerjusto structureandthermalbehavioroftanninsfromacaciadealbatabarkandtheirreactivitytowardformaldehyde AT saraviayanina structureandthermalbehavioroftanninsfromacaciadealbatabarkandtheirreactivitytowardformaldehyde AT vergaraemilio structureandthermalbehavioroftanninsfromacaciadealbatabarkandtheirreactivitytowardformaldehyde |
_version_ |
1714200900773347328 |