ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM

This research demonstrates how the sulfite content can be measured by cyclic voltammetry using a previously reported membrane absorber system, which separates efficiently sulfite present in wine. Results obtained show notably similar values to those obtained for the same wine samples using modified...

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Autores principales:	ARCE,ROXANA, BÁEZ,CARLA, MUENA,J. P, AGUIRRE,MARÍA J, ROMERO,JULIO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Materias:	wines sulfite membrane contactor aspiration method ripper method electrooxidation
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400011
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spelling	oai:scielo:S0717-970720160004000112017-01-16ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEMARCE,ROXANABÁEZ,CARLAMUENA,J. PAGUIRRE,MARÍA JROMERO,JULIO wines sulfite membrane contactor aspiration method ripper method electrooxidation This research demonstrates how the sulfite content can be measured by cyclic voltammetry using a previously reported membrane absorber system, which separates efficiently sulfite present in wine. Results obtained show notably similar values to those obtained for the same wine samples using modified Monier-Williams method (aspiration method) and Ripper method. The membrane absorber system allows the release of the free SO2 and can be used to determine the sulfur dioxide present in juices and other foods that contain high concentrations of phenols, polyphenols and other structurally related compounds that act as interferers in the electrochemical oxidation of sulfite. The absorber solution allows a direct measurement without change in pH or added electrolyte, facilitating the determination of great amounts of samples from diverse wines using only one calibration curve. In this way, a system that allows the detection of sulfite and that can be used in vineyards is obtained. Finally, the method was assessed on linearity, sensitivity, accuracy, reproducibility and repeatability, obtaining values that account for the applicability of the method.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400011en10.4067/S0717-97072016000400011
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	wines sulfite membrane contactor aspiration method ripper method electrooxidation
spellingShingle	wines sulfite membrane contactor aspiration method ripper method electrooxidation ARCE,ROXANA BÁEZ,CARLA MUENA,J. P AGUIRRE,MARÍA J ROMERO,JULIO ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
description	This research demonstrates how the sulfite content can be measured by cyclic voltammetry using a previously reported membrane absorber system, which separates efficiently sulfite present in wine. Results obtained show notably similar values to those obtained for the same wine samples using modified Monier-Williams method (aspiration method) and Ripper method. The membrane absorber system allows the release of the free SO2 and can be used to determine the sulfur dioxide present in juices and other foods that contain high concentrations of phenols, polyphenols and other structurally related compounds that act as interferers in the electrochemical oxidation of sulfite. The absorber solution allows a direct measurement without change in pH or added electrolyte, facilitating the determination of great amounts of samples from diverse wines using only one calibration curve. In this way, a system that allows the detection of sulfite and that can be used in vineyards is obtained. Finally, the method was assessed on linearity, sensitivity, accuracy, reproducibility and repeatability, obtaining values that account for the applicability of the method.
author	ARCE,ROXANA BÁEZ,CARLA MUENA,J. P AGUIRRE,MARÍA J ROMERO,JULIO
author_facet	ARCE,ROXANA BÁEZ,CARLA MUENA,J. P AGUIRRE,MARÍA J ROMERO,JULIO
author_sort	ARCE,ROXANA
title	ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
title_short	ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
title_full	ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
title_fullStr	ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
title_full_unstemmed	ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM
title_sort	electrochemical method for sulfite determination in wines by electrochemical response using a membrane absorber system
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400011
work_keys_str_mv	AT arceroxana electrochemicalmethodforsulfitedeterminationinwinesbyelectrochemicalresponseusingamembraneabsorbersystem AT baezcarla electrochemicalmethodforsulfitedeterminationinwinesbyelectrochemicalresponseusingamembraneabsorbersystem AT muenajp electrochemicalmethodforsulfitedeterminationinwinesbyelectrochemicalresponseusingamembraneabsorbersystem AT aguirremariaj electrochemicalmethodforsulfitedeterminationinwinesbyelectrochemicalresponseusingamembraneabsorbersystem AT romerojulio electrochemicalmethodforsulfitedeterminationinwinesbyelectrochemicalresponseusingamembraneabsorbersystem
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ELECTROCHEMICAL METHOD FOR SULFITE DETERMINATION IN WINES BY ELECTROCHEMICAL RESPONSE USING A MEMBRANE ABSORBER SYSTEM

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