DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS

In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by...

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Autores principales: PERALTA,CECILIA, CAMÚ,ESTEBAN, BASSI,R, VILLARROEL,MIRZA, OJEDA,JUAN, BAEZA,PATRICIO
Lenguaje:English
Publicado: Sociedad Chilena de Química 2016
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400012
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spelling oai:scielo:S0717-970720160004000122017-01-16DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTSPERALTA,CECILIACAMÚ,ESTEBANBASSI,RVILLARROEL,MIRZAOJEDA,JUANBAEZA,PATRICIO Adsorption denitrogenation nickel pyridine In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by wet impregnation to study the adsorption of pyridine by π-complexation. All the samples (supports and adsorbents) were characterized by N2 adsorption-desorption by the BET method and electrophoretic migration. The experimental results, for the three different supports, show that the adsorption capacity is better for y-Al2O3 due to its higher isoelectric point. With the incorporation of nickel, no better adsorption capacities are observed, due that the nickel incorporation diminish the zero point charges of the adsorbents.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400012en10.4067/S0717-97072016000400012
institution Scielo Chile
collection Scielo Chile
language English
topic Adsorption
denitrogenation
nickel
pyridine
spellingShingle Adsorption
denitrogenation
nickel
pyridine
PERALTA,CECILIA
CAMÚ,ESTEBAN
BASSI,R
VILLARROEL,MIRZA
OJEDA,JUAN
BAEZA,PATRICIO
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
description In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by wet impregnation to study the adsorption of pyridine by π-complexation. All the samples (supports and adsorbents) were characterized by N2 adsorption-desorption by the BET method and electrophoretic migration. The experimental results, for the three different supports, show that the adsorption capacity is better for y-Al2O3 due to its higher isoelectric point. With the incorporation of nickel, no better adsorption capacities are observed, due that the nickel incorporation diminish the zero point charges of the adsorbents.
author PERALTA,CECILIA
CAMÚ,ESTEBAN
BASSI,R
VILLARROEL,MIRZA
OJEDA,JUAN
BAEZA,PATRICIO
author_facet PERALTA,CECILIA
CAMÚ,ESTEBAN
BASSI,R
VILLARROEL,MIRZA
OJEDA,JUAN
BAEZA,PATRICIO
author_sort PERALTA,CECILIA
title DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
title_short DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
title_full DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
title_fullStr DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
title_full_unstemmed DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
title_sort denitrogenation by adsorption of pyridine on ni/support adsorbents
publisher Sociedad Chilena de Química
publishDate 2016
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400012
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AT camuesteban denitrogenationbyadsorptionofpyridineonnisupportadsorbents
AT bassir denitrogenationbyadsorptionofpyridineonnisupportadsorbents
AT villarroelmirza denitrogenationbyadsorptionofpyridineonnisupportadsorbents
AT ojedajuan denitrogenationbyadsorptionofpyridineonnisupportadsorbents
AT baezapatricio denitrogenationbyadsorptionofpyridineonnisupportadsorbents
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