DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS
In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by...
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Sociedad Chilena de Química
2016
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oai:scielo:S0717-970720160004000122017-01-16DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTSPERALTA,CECILIACAMÚ,ESTEBANBASSI,RVILLARROEL,MIRZAOJEDA,JUANBAEZA,PATRICIO Adsorption denitrogenation nickel pyridine In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by wet impregnation to study the adsorption of pyridine by π-complexation. All the samples (supports and adsorbents) were characterized by N2 adsorption-desorption by the BET method and electrophoretic migration. The experimental results, for the three different supports, show that the adsorption capacity is better for y-Al2O3 due to its higher isoelectric point. With the incorporation of nickel, no better adsorption capacities are observed, due that the nickel incorporation diminish the zero point charges of the adsorbents.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400012en10.4067/S0717-97072016000400012 |
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English |
topic |
Adsorption denitrogenation nickel pyridine |
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Adsorption denitrogenation nickel pyridine PERALTA,CECILIA CAMÚ,ESTEBAN BASSI,R VILLARROEL,MIRZA OJEDA,JUAN BAEZA,PATRICIO DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
description |
In this work we have carried out the adsorption of pyridine using three different supports (activated carbon, SiO2 and y-Al2O3). After choosing the best support, due to its higher adsorption capacity, we have impregnated the support with nickel at three different concentrations (2, 4 and 6% w/w) by wet impregnation to study the adsorption of pyridine by π-complexation. All the samples (supports and adsorbents) were characterized by N2 adsorption-desorption by the BET method and electrophoretic migration. The experimental results, for the three different supports, show that the adsorption capacity is better for y-Al2O3 due to its higher isoelectric point. With the incorporation of nickel, no better adsorption capacities are observed, due that the nickel incorporation diminish the zero point charges of the adsorbents. |
author |
PERALTA,CECILIA CAMÚ,ESTEBAN BASSI,R VILLARROEL,MIRZA OJEDA,JUAN BAEZA,PATRICIO |
author_facet |
PERALTA,CECILIA CAMÚ,ESTEBAN BASSI,R VILLARROEL,MIRZA OJEDA,JUAN BAEZA,PATRICIO |
author_sort |
PERALTA,CECILIA |
title |
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
title_short |
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
title_full |
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
title_fullStr |
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
title_full_unstemmed |
DENITROGENATION BY ADSORPTION OF PYRIDINE ON NI/SUPPORT ADSORBENTS |
title_sort |
denitrogenation by adsorption of pyridine on ni/support adsorbents |
publisher |
Sociedad Chilena de Química |
publishDate |
2016 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400012 |
work_keys_str_mv |
AT peraltacecilia denitrogenationbyadsorptionofpyridineonnisupportadsorbents AT camuesteban denitrogenationbyadsorptionofpyridineonnisupportadsorbents AT bassir denitrogenationbyadsorptionofpyridineonnisupportadsorbents AT villarroelmirza denitrogenationbyadsorptionofpyridineonnisupportadsorbents AT ojedajuan denitrogenationbyadsorptionofpyridineonnisupportadsorbents AT baezapatricio denitrogenationbyadsorptionofpyridineonnisupportadsorbents |
_version_ |
1714200901620596736 |