OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd

Pyrolysis at 800°C under air of the macromolecular precursor Chitosan•(PdCl2)n and PS-co-4-PVP•(PdCl2)n in solid state afford the mixture phases Pt/PdO depending on the molar ratio metal/polymer. For the 1:1 Chitosan•PdCl2)n and PS-co-4-PVP•(PdCl2)n precursors...

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Autores principales:	DÍAZ,CARLOS, VALENZUELA,MARÍA LUISA, RIOS,CRISTIAN, SEGOVIA,MARJORIE
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400024
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spelling	oai:scielo:S0717-970720160004000242017-01-16OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF PdDÍAZ,CARLOSVALENZUELA,MARÍA LUISARIOS,CRISTIANSEGOVIA,MARJORIEPyrolysis at 800°C under air of the macromolecular precursor Chitosan•(PdCl2)n and PS-co-4-PVP•(PdCl2)n in solid state afford the mixture phases Pt/PdO depending on the molar ratio metal/polymer. For the 1:1 Chitosan•PdCl2)n and PS-co-4-PVP•(PdCl2)n precursors the pure phase PdO was obtained while that for another molar ratios 1:5 and 1:10, the mixture phase Pt/PdO were obtained. For the 1:10 PS-co-4-PVP•(PdCl2)n precursor the core/shell PdO@Pd nanoparticles as small as 4 nm were observed. Optical properties for the PdO indicate an insulator behavior.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400024en10.4067/S0717-97072016000400024
institution	Scielo Chile
collection	Scielo Chile
language	English
description	Pyrolysis at 800°C under air of the macromolecular precursor Chitosan•(PdCl2)n and PS-co-4-PVP•(PdCl2)n in solid state afford the mixture phases Pt/PdO depending on the molar ratio metal/polymer. For the 1:1 Chitosan•PdCl2)n and PS-co-4-PVP•(PdCl2)n precursors the pure phase PdO was obtained while that for another molar ratios 1:5 and 1:10, the mixture phase Pt/PdO were obtained. For the 1:10 PS-co-4-PVP•(PdCl2)n precursor the core/shell PdO@Pd nanoparticles as small as 4 nm were observed. Optical properties for the PdO indicate an insulator behavior.
author	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA RIOS,CRISTIAN SEGOVIA,MARJORIE
spellingShingle	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA RIOS,CRISTIAN SEGOVIA,MARJORIE OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
author_facet	DÍAZ,CARLOS VALENZUELA,MARÍA LUISA RIOS,CRISTIAN SEGOVIA,MARJORIE
author_sort	DÍAZ,CARLOS
title	OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
title_short	OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
title_full	OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
title_fullStr	OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
title_full_unstemmed	OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd
title_sort	oxidation facility by a temperature dependence on the metal noble nanostructured m°/mxoy phase products using a solid state method: the case of pd
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400024
work_keys_str_mv	AT diazcarlos oxidationfacilitybyatemperaturedependenceonthemetalnoblenanostructuredmmxoyphaseproductsusingasolidstatemethodthecaseofpd AT valenzuelamarialuisa oxidationfacilitybyatemperaturedependenceonthemetalnoblenanostructuredmmxoyphaseproductsusingasolidstatemethodthecaseofpd AT rioscristian oxidationfacilitybyatemperaturedependenceonthemetalnoblenanostructuredmmxoyphaseproductsusingasolidstatemethodthecaseofpd AT segoviamarjorie oxidationfacilitybyatemperaturedependenceonthemetalnoblenanostructuredmmxoyphaseproductsusingasolidstatemethodthecaseofpd
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OXIDATION FACILITY BY A TEMPERATURE DEPENDENCE ON THE METAL NOBLE NANOSTRUCTURED M°/MxOy PHASE PRODUCTS USING A SOLID STATE METHOD: THE CASE OF Pd

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