SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)

It was successful synthesized the ion exchange resin poly([(2-methacryloyloxy) ethyl]) trimethylammonium chloride) PClMETA by radical polymerization to study the removal properties towards vanadium (V) and molybdenum (VI) and compared with the commercial resin AmberliteIRA-402 which contains the sam...

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Autores principales:	MORALES,D. V, RIVAS,B. L, GONZÁLEZ,M
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2016
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400029
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spelling	oai:scielo:S0717-970720160004000292017-01-16SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)MORALES,D. VRIVAS,B. LGONZÁLEZ,MIt was successful synthesized the ion exchange resin poly([(2-methacryloyloxy) ethyl]) trimethylammonium chloride) PClMETA by radical polymerization to study the removal properties towards vanadium (V) and molybdenum (VI) and compared with the commercial resin AmberliteIRA-402 which contains the same functional group. The resin was characterized by FT-IR and SEM. Parameters including water adsorption capacity, effect of the pH, maximum retention capacity of the metal ions, elution, regeneration, adsorption time, and adsorption isotherms were studied. All the studies were carried out in Batch and Column equilibrium procedures. Thermodynamic parameters such as enthalpy, entropy, and free energy were calculated. The PClMETA resin showed higher capacity to remove V(V) and Mo(VI) from water solution than Amberlite IRA-402 commercial resin. The higher capacity displayed by PClMETA resin was attributed to the higher degree of swelling and different structure that Amberlite IRA-402 resin.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.61 n.4 20162016-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400029en10.4067/S0717-97072016000400029
institution	Scielo Chile
collection	Scielo Chile
language	English
description	It was successful synthesized the ion exchange resin poly([(2-methacryloyloxy) ethyl]) trimethylammonium chloride) PClMETA by radical polymerization to study the removal properties towards vanadium (V) and molybdenum (VI) and compared with the commercial resin AmberliteIRA-402 which contains the same functional group. The resin was characterized by FT-IR and SEM. Parameters including water adsorption capacity, effect of the pH, maximum retention capacity of the metal ions, elution, regeneration, adsorption time, and adsorption isotherms were studied. All the studies were carried out in Batch and Column equilibrium procedures. Thermodynamic parameters such as enthalpy, entropy, and free energy were calculated. The PClMETA resin showed higher capacity to remove V(V) and Mo(VI) from water solution than Amberlite IRA-402 commercial resin. The higher capacity displayed by PClMETA resin was attributed to the higher degree of swelling and different structure that Amberlite IRA-402 resin.
author	MORALES,D. V RIVAS,B. L GONZÁLEZ,M
spellingShingle	MORALES,D. V RIVAS,B. L GONZÁLEZ,M SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
author_facet	MORALES,D. V RIVAS,B. L GONZÁLEZ,M
author_sort	MORALES,D. V
title	SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
title_short	SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
title_full	SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
title_fullStr	SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
title_full_unstemmed	SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)
title_sort	synthesis and characterization of poly([(2-methacryloyloxy) ethyl]) trimethylamonnium chloride) resin with removal properties for vanadium(v) and molybdenum(vi)
publisher	Sociedad Chilena de Química
publishDate	2016
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072016000400029
work_keys_str_mv	AT moralesdv synthesisandcharacterizationofpoly2methacryloyloxyethyltrimethylamonniumchlorideresinwithremovalpropertiesforvanadiumvandmolybdenumvi AT rivasbl synthesisandcharacterizationofpoly2methacryloyloxyethyltrimethylamonniumchlorideresinwithremovalpropertiesforvanadiumvandmolybdenumvi AT gonzalezm synthesisandcharacterizationofpoly2methacryloyloxyethyltrimethylamonniumchlorideresinwithremovalpropertiesforvanadiumvandmolybdenumvi
_version_	1714200904605892608

SYNTHESIS AND CHARACTERIZATION OF POLY([(2-methacryloyloxy) ethyl]) TRIMETHYLAMONNIUM CHLORIDE) RESIN WITH REMOVAL PROPERTIES FOR VANADIUM(V) AND MOLYBDENUM(VI)

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