SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE

The new complex of [Hg(2-AMPy)2Br]2.HgBr4 (1) was synthesized from the reaction of HgBr2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment was obtained by slow evaporation from DMSO. Resulted complex was characterized by IR, elemental ana...

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Autores principales:	SHIRVAN,SADIF A, KHAZALI,FEREYDOON, DEZFULI,SARA HAYDARI, BORSALANI,ALI
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2017
Materias:	Hg(II) 2-(aminomethyl)pyridine ligand crystal structure thermal gravimetric analyses
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100009
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spelling	oai:scielo:S0717-970720170001000092017-05-05SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDESHIRVAN,SADIF AKHAZALI,FEREYDOONDEZFULI,SARA HAYDARIBORSALANI,ALI Hg(II) 2-(aminomethyl)pyridine ligand crystal structure thermal gravimetric analyses The new complex of [Hg(2-AMPy)2Br]2.HgBr4 (1) was synthesized from the reaction of HgBr2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment was obtained by slow evaporation from DMSO. Resulted complex was characterized by IR, elemental analysis, thermal analysis and single crystal X-ray diffraction. In this compound, two five-coordinated mercury centers in the cationic parts have slightly and highly distorted square-based pyramidal geometries by the trigonal-indexes, τ5, of 0.18 and 0.49, respectively. According to four-coordinate geometry index, τ4, of 0.95, anionic part has perfect tetrahedral geometry.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.1 20172017-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100009en10.4067/S0717-97072017000100009
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Hg(II) 2-(aminomethyl)pyridine ligand crystal structure thermal gravimetric analyses
spellingShingle	Hg(II) 2-(aminomethyl)pyridine ligand crystal structure thermal gravimetric analyses SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
description	The new complex of [Hg(2-AMPy)2Br]2.HgBr4 (1) was synthesized from the reaction of HgBr2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment was obtained by slow evaporation from DMSO. Resulted complex was characterized by IR, elemental analysis, thermal analysis and single crystal X-ray diffraction. In this compound, two five-coordinated mercury centers in the cationic parts have slightly and highly distorted square-based pyramidal geometries by the trigonal-indexes, τ5, of 0.18 and 0.49, respectively. According to four-coordinate geometry index, τ4, of 0.95, anionic part has perfect tetrahedral geometry.
author	SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI
author_facet	SHIRVAN,SADIF A KHAZALI,FEREYDOON DEZFULI,SARA HAYDARI BORSALANI,ALI
author_sort	SHIRVAN,SADIF A
title	SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
title_short	SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
title_full	SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
title_fullStr	SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
title_full_unstemmed	SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE
title_sort	synthesis, crystal structure analysis and characterization of mercury(ii) complex containing 2-(aminomethyl)pyridine and bromide
publisher	Sociedad Chilena de Química
publishDate	2017
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100009
work_keys_str_mv	AT shirvansadifa synthesiscrystalstructureanalysisandcharacterizationofmercuryiicomplexcontaining2aminomethylpyridineandbromide AT khazalifereydoon synthesiscrystalstructureanalysisandcharacterizationofmercuryiicomplexcontaining2aminomethylpyridineandbromide AT dezfulisarahaydari synthesiscrystalstructureanalysisandcharacterizationofmercuryiicomplexcontaining2aminomethylpyridineandbromide AT borsalaniali synthesiscrystalstructureanalysisandcharacterizationofmercuryiicomplexcontaining2aminomethylpyridineandbromide
_version_	1714200906373791744

SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE

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