TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM

Two novel porphyrinic compounds, {Zn[TCPP(CH2CH3)2(CH3)2]}n (1) and TCPP(CH3)4 (2) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), with the TCPP(CH2CH3)2(CH3)2 and TCPP(CH3)4 generated in situ, have been synthesized via a solvothermal reaction and structurally characterized by single-crystal X-ray di...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	ZHANG,DING-WA, CHEN,WEN-TONG
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2017
Materias:	esterification in situ porphyrin TCPP zinc
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100015
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072017000100015
record_format	dspace
spelling	oai:scielo:S0717-970720170001000152017-05-05TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISMZHANG,DING-WACHEN,WEN-TONG esterification in situ porphyrin TCPP zinc Two novel porphyrinic compounds, {Zn[TCPP(CH2CH3)2(CH3)2]}n (1) and TCPP(CH3)4 (2) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), with the TCPP(CH2CH3)2(CH3)2 and TCPP(CH3)4 generated in situ, have been synthesized via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 is characteristic of a two-dimensional (2-D) coordination polymer, based on the zinc ion coordinating to four nitrogen atoms and two oxygen atoms. Compound 1 possesses a large void space (220 Â³) corresponding to 4.6% of the unit-cell volume. Compound 2 is characterized by an isolated structure. The reaction mechanism of preparing both compounds was explored. The photoluminescence properties, FT-IR, UV-vis absorption spectra, fluorescence lifetime and fluorescence quantum yield of TCPP were also reported.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.1 20172017-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100015en10.4067/S0717-97072017000100015
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	esterification in situ porphyrin TCPP zinc
spellingShingle	esterification in situ porphyrin TCPP zinc ZHANG,DING-WA CHEN,WEN-TONG TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
description	Two novel porphyrinic compounds, {Zn[TCPP(CH2CH3)2(CH3)2]}n (1) and TCPP(CH3)4 (2) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), with the TCPP(CH2CH3)2(CH3)2 and TCPP(CH3)4 generated in situ, have been synthesized via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 is characteristic of a two-dimensional (2-D) coordination polymer, based on the zinc ion coordinating to four nitrogen atoms and two oxygen atoms. Compound 1 possesses a large void space (220 Â³) corresponding to 4.6% of the unit-cell volume. Compound 2 is characterized by an isolated structure. The reaction mechanism of preparing both compounds was explored. The photoluminescence properties, FT-IR, UV-vis absorption spectra, fluorescence lifetime and fluorescence quantum yield of TCPP were also reported.
author	ZHANG,DING-WA CHEN,WEN-TONG
author_facet	ZHANG,DING-WA CHEN,WEN-TONG
author_sort	ZHANG,DING-WA
title	TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
title_short	TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
title_full	TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
title_fullStr	TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
title_full_unstemmed	TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM
title_sort	two novel tcpp porphyrinic compounds: in situ syntheses, characterization and reaction mechanism
publisher	Sociedad Chilena de Química
publishDate	2017
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100015
work_keys_str_mv	AT zhangdingwa twonoveltcppporphyriniccompoundsinsitusynthesescharacterizationandreactionmechanism AT chenwentong twonoveltcppporphyriniccompoundsinsitusynthesescharacterizationandreactionmechanism
_version_	1714200907385667584

TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM

Ejemplares similares