IMPROVE THE CATALYTIC ACTIVITY OF FEOOH/BENTONITE MATERIAL BY MECHANICAL ACTIVATION

To improve the catalytic activity of FeOOH/bentonite material used in Fenton-like process, the activation of FeOOH/bentonite by mechanical activation was studied. The optimum conditions for activation of FeOOH/bentonite were as follows: filling ratio of grinding medium 30%, "15 mL of D06 balls...

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Autores principales: WEI,GUANGTAO, LI,ZHONGMIN, ZHANG,LINYE, DENG,YUE, SHAO,LUHUA, LIU,ZIHAN
Lenguaje:English
Publicado: Sociedad Chilena de Química 2017
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000100021
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Sumario:To improve the catalytic activity of FeOOH/bentonite material used in Fenton-like process, the activation of FeOOH/bentonite by mechanical activation was studied. The optimum conditions for activation of FeOOH/bentonite were as follows: filling ratio of grinding medium 30%, "15 mL of D06 balls plus 15 mL of D10 balls" as combination mode of grinding medium, rotation speed of planet carrier 600 rpm, milling time 40 min, and powder-to-ball ratio 0.5:30 (g•mL-1). The mechanical activation was an effective method to improve the catalytic activity of FeOOH/bentonite. Both the lattice distortion and crystal size decrease happened in α-FeOOH and the change of layer structure of bentonite were contributed to the increase of catalytic activity of activated FeOOH/bentonite.