SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS

In this study Methyl Isobutyl Ketone (MIBK) and acetophenone (Methyl Phenyl Ketone) are presented as suitable agents for removal of Fe(III) from concentrated hydrochloric acid solutions. An extensive study applying 4 parameters was carried out: Time (5, 10,15,20,30 and 60 minutes), Stirring rate (20...

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Autores principales: FAROUQ,RAMA, SELIM,YEHIA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2017
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000200002
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spelling oai:scielo:S0717-970720170002000022017-06-30SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONSFAROUQ,RAMASELIM,YEHIA Fe(III) Solvation mechanism Hydrochloric acid MIBK acetophenone In this study Methyl Isobutyl Ketone (MIBK) and acetophenone (Methyl Phenyl Ketone) are presented as suitable agents for removal of Fe(III) from concentrated hydrochloric acid solutions. An extensive study applying 4 parameters was carried out: Time (5, 10,15,20,30 and 60 minutes), Stirring rate (200, 300, 400 and 500 r.p.m), Solvent to HCl Ratio (5%, 10%, 14% and 16%), and initial concentration of Fe ions in crude HCl (95.24, 126 ppm, 330 ppm and 1955 ppm).The best Condition was found to be 30 min - 400 r.p.m - 14 %. The distilled water was used to strip Fe ions out of MIBK; In order to get most of the MIBK dissolved in both the concentrated HCl and water. Diluents were used such as benzene, kerosene and xylene. Xylene gives better recovery of about 96%.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.2 20172017-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000200002en10.4067/S0717-97072017000200002
institution Scielo Chile
collection Scielo Chile
language English
topic Fe(III)
Solvation mechanism
Hydrochloric acid
MIBK
acetophenone
spellingShingle Fe(III)
Solvation mechanism
Hydrochloric acid
MIBK
acetophenone
FAROUQ,RAMA
SELIM,YEHIA
SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
description In this study Methyl Isobutyl Ketone (MIBK) and acetophenone (Methyl Phenyl Ketone) are presented as suitable agents for removal of Fe(III) from concentrated hydrochloric acid solutions. An extensive study applying 4 parameters was carried out: Time (5, 10,15,20,30 and 60 minutes), Stirring rate (200, 300, 400 and 500 r.p.m), Solvent to HCl Ratio (5%, 10%, 14% and 16%), and initial concentration of Fe ions in crude HCl (95.24, 126 ppm, 330 ppm and 1955 ppm).The best Condition was found to be 30 min - 400 r.p.m - 14 %. The distilled water was used to strip Fe ions out of MIBK; In order to get most of the MIBK dissolved in both the concentrated HCl and water. Diluents were used such as benzene, kerosene and xylene. Xylene gives better recovery of about 96%.
author FAROUQ,RAMA
SELIM,YEHIA
author_facet FAROUQ,RAMA
SELIM,YEHIA
author_sort FAROUQ,RAMA
title SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
title_short SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
title_full SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
title_fullStr SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
title_full_unstemmed SOLVENT EXTRACTION OF IRON IONS FROM HYDROCHLORIC ACID SOLUTIONS
title_sort solvent extraction of iron ions from hydrochloric acid solutions
publisher Sociedad Chilena de Química
publishDate 2017
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000200002
work_keys_str_mv AT farouqrama solventextractionofironionsfromhydrochloricacidsolutions
AT selimyehia solventextractionofironionsfromhydrochloricacidsolutions
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