THEORETICAL STUDY OF THE PH3-ASSISTED MIGRATION OF A COORDINATED ARYL GROUP TO A COORDINATED CO IN THE COMPLEXES RhCpI(CO)(p-XC6H4)

THEORETICAL STUDY OF THE PH3-ASSISTED MIGRATION OF A COORDINATED ARYL GROUP TO A COORDINATED CO IN THE COMPLEXES RhCpI(CO)(p-XC6H4)

We report the results of theoretical mechanistic studies on PH3-assisted migration of a coordinated aryl group to a coordinated CO in the complexes RhCpI(CO) (p-XC6H4). The X-substituent effect on thermodynamic and kinetic parameters was explored. The progress of the reaction was quantitatively stud...

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Autores principales: GHIASI,REZA, SADEGHI,NASRIN, JAMEHBOZORGI,SAEID
Lenguaje:English
Publicado: Sociedad Chilena de Química 2017
Materias:
Insertion reaction
Substituent effect
Thermodynamic parameters
Kinetic parameters
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000200007
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