CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES

ABSTRACT We report here a facile, mild and efficient synthesis of functionalized tetrahydropyrimidine quinolones via one pot three-component condensation of aromatic aldehydes, N,N-dimethyl barbituricacid (barbituricacid), 4-hydroxy-1-methylquinolin-2(1H)-one and using a cerium ammonium nitrate (CAN...

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Autores principales:	GERAMIZADEGAN,MAHSA, MAHDAVINIA,GHOLAM HOSSEIN
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2017
Materias:	Tetrahydropyrimidine quinolones One-pot Multi-component Green chemistry Cerium ammonium nitrate
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000303578
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spelling	oai:scielo:S0717-970720170003035782017-09-08CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONESGERAMIZADEGAN,MAHSAMAHDAVINIA,GHOLAM HOSSEIN Tetrahydropyrimidine quinolones One-pot Multi-component Green chemistry Cerium ammonium nitrate ABSTRACT We report here a facile, mild and efficient synthesis of functionalized tetrahydropyrimidine quinolones via one pot three-component condensation of aromatic aldehydes, N,N-dimethyl barbituricacid (barbituricacid), 4-hydroxy-1-methylquinolin-2(1H)-one and using a cerium ammonium nitrate (CAN) as a green catalyst in aqueous media-water (as a green ideal solvent) is described. The significant advantages of this protocol are short reaction time, simple work up procedure and reduced environmental impact, wide substrate scope; generally very good to excellent yields and starting materials are inexpensive and commercially available. The structures of these compounds were established on the basis of IR, 1H NMR, 13C NMR spectra.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.3 20172017-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000303578en10.4067/s0717-97072017000303578
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Tetrahydropyrimidine quinolones One-pot Multi-component Green chemistry Cerium ammonium nitrate
spellingShingle	Tetrahydropyrimidine quinolones One-pot Multi-component Green chemistry Cerium ammonium nitrate GERAMIZADEGAN,MAHSA MAHDAVINIA,GHOLAM HOSSEIN CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
description	ABSTRACT We report here a facile, mild and efficient synthesis of functionalized tetrahydropyrimidine quinolones via one pot three-component condensation of aromatic aldehydes, N,N-dimethyl barbituricacid (barbituricacid), 4-hydroxy-1-methylquinolin-2(1H)-one and using a cerium ammonium nitrate (CAN) as a green catalyst in aqueous media-water (as a green ideal solvent) is described. The significant advantages of this protocol are short reaction time, simple work up procedure and reduced environmental impact, wide substrate scope; generally very good to excellent yields and starting materials are inexpensive and commercially available. The structures of these compounds were established on the basis of IR, 1H NMR, 13C NMR spectra.
author	GERAMIZADEGAN,MAHSA MAHDAVINIA,GHOLAM HOSSEIN
author_facet	GERAMIZADEGAN,MAHSA MAHDAVINIA,GHOLAM HOSSEIN
author_sort	GERAMIZADEGAN,MAHSA
title	CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
title_short	CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
title_full	CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
title_fullStr	CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
title_full_unstemmed	CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES
title_sort	cerium (iv) ammonium nitrate (can) as a catalyst in water: a simple, proficient and green approach for the synthesis of tetrahydropyrimidine quinolones
publisher	Sociedad Chilena de Química
publishDate	2017
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000303578
work_keys_str_mv	AT geramizadeganmahsa ceriumivammoniumnitratecanasacatalystinwaterasimpleproficientandgreenapproachforthesynthesisoftetrahydropyrimidinequinolones AT mahdaviniagholamhossein ceriumivammoniumnitratecanasacatalystinwaterasimpleproficientandgreenapproachforthesynthesisoftetrahydropyrimidinequinolones
_version_	1714200913861672960

CERIUM (IV) AMMONIUM NITRATE (CAN) AS A CATALYST IN WATER: A SIMPLE, PROFICIENT AND GREEN APPROACH FOR THE SYNTHESIS OF TETRAHYDROPYRIMIDINE QUINOLONES

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