SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE

SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE

ABSTRACT Inorganic-organic hybrid structures based on metal-complexes particularly, octahedral bis-2,2′:6′,2″- terpyridine metal complexes provide an advantages of increased symmetry and in the case of ruthenium(III)/ruthenium(II) complexation an entrance to a directed...

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Autores principales: MARGANDAN,K, JEBASTIN,SONIA JAS M
Lenguaje:English
Publicado: Sociedad Chilena de Química 2017
Materias:
Ru(II) terpyridine
Au nanopaprticles
thiolates
electro catalytic reduction of nitrite
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403691
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spelling oai:scielo:S0717-970720170004036912018-04-02SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITEMARGANDAN,KJEBASTIN,SONIA JAS M Ru(II) terpyridine Au nanopaprticles thiolates electro catalytic reduction of nitrite ABSTRACT Inorganic-organic hybrid structures based on metal-complexes particularly, octahedral bis-2,2′:6′,2″- terpyridine metal complexes provide an advantages of increased symmetry and in the case of ruthenium(III)/ruthenium(II) complexation an entrance to a directed complexation Method. The Ru (II) terpyridine methane thiolate protected gold nanoparticle was synthesized through covalent bonding of Ru terpyridine methane thiolates over gold nanoparticles surfaces. The ligand terpyridine methanethiolate was synthesized successfully in good percentage of yield. The structures were confirmed and characterized by different physical, analytical, spectral data like FTIR, UV, SEM and Cyclic voltammetry. All the data are shown the expected results.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.4 20172017-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403691en10.4067/s0717-97072017000403691
institution Scielo Chile
collection Scielo Chile
language English
topic Ru(II) terpyridine
Au nanopaprticles
thiolates
electro catalytic reduction of nitrite
spellingShingle Ru(II) terpyridine
Au nanopaprticles
thiolates
electro catalytic reduction of nitrite
MARGANDAN,K
JEBASTIN,SONIA JAS M
SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
description ABSTRACT Inorganic-organic hybrid structures based on metal-complexes particularly, octahedral bis-2,2′:6′,2″- terpyridine metal complexes provide an advantages of increased symmetry and in the case of ruthenium(III)/ruthenium(II) complexation an entrance to a directed complexation Method. The Ru (II) terpyridine methane thiolate protected gold nanoparticle was synthesized through covalent bonding of Ru terpyridine methane thiolates over gold nanoparticles surfaces. The ligand terpyridine methanethiolate was synthesized successfully in good percentage of yield. The structures were confirmed and characterized by different physical, analytical, spectral data like FTIR, UV, SEM and Cyclic voltammetry. All the data are shown the expected results.
author MARGANDAN,K
JEBASTIN,SONIA JAS M
author_facet MARGANDAN,K
JEBASTIN,SONIA JAS M
author_sort MARGANDAN,K
title SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
title_short SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
title_full SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
title_fullStr SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
title_full_unstemmed SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2′:6′, 2″-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
title_sort synthesis and characterization of bismercapto (2, 2′:6′, 2″-terpyridine) ru(ii)-complexes stabilized gold nanoparticles and their electro catalytic reduction of nitrite
publisher Sociedad Chilena de Química
publishDate 2017
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403691
work_keys_str_mv AT margandank synthesisandcharacterizationofbismercapto2282426824228243terpyridineruiicomplexesstabilizedgoldnanoparticlesandtheirelectrocatalyticreductionofnitrite
AT jebastinsoniajasm synthesisandcharacterizationofbismercapto2282426824228243terpyridineruiicomplexesstabilizedgoldnanoparticlesandtheirelectrocatalyticreductionofnitrite
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