ANODIC STRIPPING VOLTAMMETRIC DETERMINATION OF LEAD USING A CHEMICALLY MODIFIED ELECTRODE BASED ON AZA CROWN ETHER
A glassy carbon electrode was modified by drop-coating technique using 1,4,10,13-Tetraoxa-7,16-diazaciclooctadecano (diaza-18 -crown-6 or DA18C6) and Nafion (NF) for the determination of Pb (II) by square wave anodic stripping voltammetric (SWASV). The new electrode exhibits an increase in due to ma...
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| Autores principales: | , , , , , |
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| Lenguaje: | English |
| Publicado: |
Sociedad Chilena de Química
2017
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| Materias: | |
| Acceso en línea: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403726 |
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| Sumario: | A glassy carbon electrode was modified by drop-coating technique using 1,4,10,13-Tetraoxa-7,16-diazaciclooctadecano (diaza-18 -crown-6 or DA18C6) and Nafion (NF) for the determination of Pb (II) by square wave anodic stripping voltammetric (SWASV). The new electrode exhibits an increase in due to major pre-concentration of aza crown ether and ionic exchange of NF with metal cations. Optimal conditions were: 3 mmol L-1 DA18C6, 3 wt % NF, 10 mmol L-1 HCl as supporting electrolyte, a frequency of 15 Hz, an accumulation time of 300 s and an accumulation potential of -0.80 V. The detection limit was 0.09 μg L-1 and linear range was 10-50 μg L-1. Interference from metal ions such us Fe (II), Pb (II), Cd (II) and Cu (II) was also studied. The method is sensitive, selective and simple with a relative standard deviation of 11%. |
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