CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED

ABSTRACT The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 °C and 3MPa of H2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, γ...

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Autores principales:	BASSI,ROMINA, CAMÚ,ESTEBAN, VILLARROEL,MIRZA, GIL-LLAMBÍAS,FCO. JAVIER, GARCÍA-FIERRO,J. L., ESCALONA,NÉSTOR, BAEZA,PATRICIO
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2017
Materias:	Quinoline support Carbon sulphide
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403779
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spelling	oai:scielo:S0717-970720170004037792018-04-02CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEEDBASSI,ROMINACAMÚ,ESTEBANVILLARROEL,MIRZAGIL-LLAMBÍAS,FCO. JAVIERGARCÍA-FIERRO,J. L.ESCALONA,NÉSTORBAEZA,PATRICIO Quinoline support Carbon sulphide ABSTRACT The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 °C and 3MPa of H2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, γ-Al2O3 and SiO2 supports. The activity trend was correlated with the Re dispersion on the support. The effect of the addition of CS2 was increased activity until 2.5 v/v % content. At higher CS2 content the activity decreased due to competitive adsorption between CS2 and Quinoline on the active sites.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.62 n.4 20172017-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403779en10.4067/s0717-97072017000403779
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Quinoline support Carbon sulphide
spellingShingle	Quinoline support Carbon sulphide BASSI,ROMINA CAMÚ,ESTEBAN VILLARROEL,MIRZA GIL-LLAMBÍAS,FCO. JAVIER GARCÍA-FIERRO,J. L. ESCALONA,NÉSTOR BAEZA,PATRICIO CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
description	ABSTRACT The effect of supports and the addition of CS2 in the feed were studied on hydrodenitrogenation of Quinoline in a continuous flow reactor over ReS2/support catalysts at 300, 325 and 350 °C and 3MPa of H2. The ReS2 supported on TiO2 displayed the highest activity followed by ZrO2, γ-Al2O3 and SiO2 supports. The activity trend was correlated with the Re dispersion on the support. The effect of the addition of CS2 was increased activity until 2.5 v/v % content. At higher CS2 content the activity decreased due to competitive adsorption between CS2 and Quinoline on the active sites.
author	BASSI,ROMINA CAMÚ,ESTEBAN VILLARROEL,MIRZA GIL-LLAMBÍAS,FCO. JAVIER GARCÍA-FIERRO,J. L. ESCALONA,NÉSTOR BAEZA,PATRICIO
author_facet	BASSI,ROMINA CAMÚ,ESTEBAN VILLARROEL,MIRZA GIL-LLAMBÍAS,FCO. JAVIER GARCÍA-FIERRO,J. L. ESCALONA,NÉSTOR BAEZA,PATRICIO
author_sort	BASSI,ROMINA
title	CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
title_short	CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
title_full	CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
title_fullStr	CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
title_full_unstemmed	CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED
title_sort	conversion of quinoline on res2 catalysts: effect of the support and the addition of cs2 in the feed
publisher	Sociedad Chilena de Química
publishDate	2017
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072017000403779
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CONVERSION OF QUINOLINE ON ReS2 CATALYSTS: EFFECT OF THE SUPPORT AND THE ADDITION OF CS2 IN THE FEED

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