CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER

ABSTRACT In this paper, the zinc carbonate hydroxide (Zn5(OH) 6(CO2)2, ZCHO) was prepared by a facile hydrothermal method assisted chitosan (CS). The as-prepared product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TG). Results indi...

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Autores principales: Liu,Peili, Li,Yao, Xu,Yeping, Qing,Ye, Han,Chengliang
Lenguaje:English
Publicado: Sociedad Chilena de Química 2018
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103819
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spelling oai:scielo:S0717-970720180001038192018-05-11CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATERLiu,PeiliLi,YaoXu,YepingQing,YeHan,Chengliang Zinc carbonate hydroxide Chitosan Freundlich model Removal of Cu2+ ABSTRACT In this paper, the zinc carbonate hydroxide (Zn5(OH) 6(CO2)2, ZCHO) was prepared by a facile hydrothermal method assisted chitosan (CS). The as-prepared product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TG). Results indicated that every micro-sized ZCHO particle had a multi-layered structure and was composed of many ZCHO nanoplates. The used CS played the role of the template in the formation of well multi-layered ZCHO particles. TG measurements had further indicated that the remained content of CS in the as-prepared ZCHO powders was about 8 Wt.%. The adsorption isotherm results showed that the ZCHO powders with CS exhibited massive removal of Cu2+ from aqueous solution at room temperature. The equilibrium adsorption was well described by the Freundlich isotherm model. Based on the above experimental results, the possible removal mechanism of Cu2+ by the multi-layered ZCHO was proposed.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.1 20182018-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103819en10.4067/s0717-97072018000103819
institution Scielo Chile
collection Scielo Chile
language English
topic Zinc carbonate hydroxide
Chitosan
Freundlich model
Removal of Cu2+
spellingShingle Zinc carbonate hydroxide
Chitosan
Freundlich model
Removal of Cu2+
Liu,Peili
Li,Yao
Xu,Yeping
Qing,Ye
Han,Chengliang
CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
description ABSTRACT In this paper, the zinc carbonate hydroxide (Zn5(OH) 6(CO2)2, ZCHO) was prepared by a facile hydrothermal method assisted chitosan (CS). The as-prepared product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TG). Results indicated that every micro-sized ZCHO particle had a multi-layered structure and was composed of many ZCHO nanoplates. The used CS played the role of the template in the formation of well multi-layered ZCHO particles. TG measurements had further indicated that the remained content of CS in the as-prepared ZCHO powders was about 8 Wt.%. The adsorption isotherm results showed that the ZCHO powders with CS exhibited massive removal of Cu2+ from aqueous solution at room temperature. The equilibrium adsorption was well described by the Freundlich isotherm model. Based on the above experimental results, the possible removal mechanism of Cu2+ by the multi-layered ZCHO was proposed.
author Liu,Peili
Li,Yao
Xu,Yeping
Qing,Ye
Han,Chengliang
author_facet Liu,Peili
Li,Yao
Xu,Yeping
Qing,Ye
Han,Chengliang
author_sort Liu,Peili
title CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
title_short CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
title_full CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
title_fullStr CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
title_full_unstemmed CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF CU2+ FROM WATER
title_sort chitosan assisted synthesis of multi-layered zinc carbonate hydroxides for massive removal of cu2+ from water
publisher Sociedad Chilena de Química
publishDate 2018
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103819
work_keys_str_mv AT liupeili chitosanassistedsynthesisofmultilayeredzinccarbonatehydroxidesformassiveremovalofcu2fromwater
AT liyao chitosanassistedsynthesisofmultilayeredzinccarbonatehydroxidesformassiveremovalofcu2fromwater
AT xuyeping chitosanassistedsynthesisofmultilayeredzinccarbonatehydroxidesformassiveremovalofcu2fromwater
AT qingye chitosanassistedsynthesisofmultilayeredzinccarbonatehydroxidesformassiveremovalofcu2fromwater
AT hanchengliang chitosanassistedsynthesisofmultilayeredzinccarbonatehydroxidesformassiveremovalofcu2fromwater
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