Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K

ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The exper...

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Autores principales: Maharolkar,Aruna P., Murugkar,A. G., Khirade,P W.
Lenguaje:English
Publicado: Sociedad Chilena de Química 2018
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103841
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spelling oai:scielo:S0717-970720180001038412018-05-11Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 KMaharolkar,Aruna P.Murugkar,A. G.Khirade,P W. excess static dielectric constant R-K fit equation ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The experimental data further used to determine the Bruggeman factor, and excess properties viz. excess density, excess viscosity, and excess refractive index. The values of excess properties further fitted with Redlich-Kister equation. Excess properties were used to indicate the presence of intermolecular interactions and strength of intermolecular interactions between the molecules in the binary mixturesinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.1 20182018-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103841en10.4067/s0717-97072018000103841
institution Scielo Chile
collection Scielo Chile
language English
topic excess static dielectric constant
R-K fit equation
spellingShingle excess static dielectric constant
R-K fit equation
Maharolkar,Aruna P.
Murugkar,A. G.
Khirade,P W.
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
description ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The experimental data further used to determine the Bruggeman factor, and excess properties viz. excess density, excess viscosity, and excess refractive index. The values of excess properties further fitted with Redlich-Kister equation. Excess properties were used to indicate the presence of intermolecular interactions and strength of intermolecular interactions between the molecules in the binary mixtures
author Maharolkar,Aruna P.
Murugkar,A. G.
Khirade,P W.
author_facet Maharolkar,Aruna P.
Murugkar,A. G.
Khirade,P W.
author_sort Maharolkar,Aruna P.
title Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
title_short Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
title_full Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
title_fullStr Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
title_full_unstemmed Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
title_sort dielectric & physiochemical characterization of nitromethane with dmso at 293.15 k
publisher Sociedad Chilena de Química
publishDate 2018
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103841
work_keys_str_mv AT maharolkararunap dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k
AT murugkarag dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k
AT khiradepw dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k
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