Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K
ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The exper...
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Sociedad Chilena de Química
2018
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oai:scielo:S0717-970720180001038412018-05-11Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 KMaharolkar,Aruna P.Murugkar,A. G.Khirade,P W. excess static dielectric constant R-K fit equation ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The experimental data further used to determine the Bruggeman factor, and excess properties viz. excess density, excess viscosity, and excess refractive index. The values of excess properties further fitted with Redlich-Kister equation. Excess properties were used to indicate the presence of intermolecular interactions and strength of intermolecular interactions between the molecules in the binary mixturesinfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.1 20182018-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103841en10.4067/s0717-97072018000103841 |
| institution |
Scielo Chile |
| collection |
Scielo Chile |
| language |
English |
| topic |
excess static dielectric constant R-K fit equation |
| spellingShingle |
excess static dielectric constant R-K fit equation Maharolkar,Aruna P. Murugkar,A. G. Khirade,P W. Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| description |
ABSTRACT The present paper reports study of dielectric & physicochemical properties like dielectric constant, viscosity, density and refractive index for the binary mixtures of Nitromethane (NM) and Dimethylsulphoxide (DMSO) over the entire concentration range were measured at 293.15K. The experimental data further used to determine the Bruggeman factor, and excess properties viz. excess density, excess viscosity, and excess refractive index. The values of excess properties further fitted with Redlich-Kister equation. Excess properties were used to indicate the presence of intermolecular interactions and strength of intermolecular interactions between the molecules in the binary mixtures |
| author |
Maharolkar,Aruna P. Murugkar,A. G. Khirade,P W. |
| author_facet |
Maharolkar,Aruna P. Murugkar,A. G. Khirade,P W. |
| author_sort |
Maharolkar,Aruna P. |
| title |
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| title_short |
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| title_full |
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| title_fullStr |
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| title_full_unstemmed |
Dielectric & Physiochemical Characterization of Nitromethane with DMSO at 293.15 K |
| title_sort |
dielectric & physiochemical characterization of nitromethane with dmso at 293.15 k |
| publisher |
Sociedad Chilena de Química |
| publishDate |
2018 |
| url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000103841 |
| work_keys_str_mv |
AT maharolkararunap dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k AT murugkarag dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k AT khiradepw dielectricampphysiochemicalcharacterizationofnitromethanewithdmsoat29315k |
| _version_ |
1714200921884327936 |