SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO

ABSTRACT An amidoxime containing 2-phenyl-1H-benzimidazole derivative, 4-(1H-Benzoimidazol-2-yl)-N-hydroxy-benzamidine, was synthesized by conversion of nitrile group of previously synthesized 2-(4-cyanophenyl)-1H-benzimidazole by treatment with hydroxylamine under alkaline solution. Characterizatio...

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Autores principales: Rahman,Mohammad Nahidur, Bhowmick,Rina Rani, Nurnabi,Mohammad, Molla,Ashraful Islam
Lenguaje:English
Publicado: Sociedad Chilena de Química 2018
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304047
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Sumario:ABSTRACT An amidoxime containing 2-phenyl-1H-benzimidazole derivative, 4-(1H-Benzoimidazol-2-yl)-N-hydroxy-benzamidine, was synthesized by conversion of nitrile group of previously synthesized 2-(4-cyanophenyl)-1H-benzimidazole by treatment with hydroxylamine under alkaline solution. Characterization of both compounds was carried out by using UV-Vis, FT-IR, 1NMR and 13C NMR, and mass spectroscopic technique. Its photophysical behavior was compared in methanol and DMSO under basic condition.