SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO

ABSTRACT An amidoxime containing 2-phenyl-1H-benzimidazole derivative, 4-(1H-Benzoimidazol-2-yl)-N-hydroxy-benzamidine, was synthesized by conversion of nitrile group of previously synthesized 2-(4-cyanophenyl)-1H-benzimidazole by treatment with hydroxylamine under alkaline solution. Characterizatio...

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Autores principales:	Rahman,Mohammad Nahidur, Bhowmick,Rina Rani, Nurnabi,Mohammad, Molla,Ashraful Islam
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2018
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304047
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spelling	oai:scielo:S0717-970720180003040472018-10-03SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSORahman,Mohammad NahidurBhowmick,Rina RaniNurnabi,MohammadMolla,Ashraful IslamABSTRACT An amidoxime containing 2-phenyl-1H-benzimidazole derivative, 4-(1H-Benzoimidazol-2-yl)-N-hydroxy-benzamidine, was synthesized by conversion of nitrile group of previously synthesized 2-(4-cyanophenyl)-1H-benzimidazole by treatment with hydroxylamine under alkaline solution. Characterization of both compounds was carried out by using UV-Vis, FT-IR, 1NMR and 13C NMR, and mass spectroscopic technique. Its photophysical behavior was compared in methanol and DMSO under basic condition.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.3 20182018-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304047en10.4067/s0717-97072018000304047
institution	Scielo Chile
collection	Scielo Chile
language	English
description	ABSTRACT An amidoxime containing 2-phenyl-1H-benzimidazole derivative, 4-(1H-Benzoimidazol-2-yl)-N-hydroxy-benzamidine, was synthesized by conversion of nitrile group of previously synthesized 2-(4-cyanophenyl)-1H-benzimidazole by treatment with hydroxylamine under alkaline solution. Characterization of both compounds was carried out by using UV-Vis, FT-IR, 1NMR and 13C NMR, and mass spectroscopic technique. Its photophysical behavior was compared in methanol and DMSO under basic condition.
author	Rahman,Mohammad Nahidur Bhowmick,Rina Rani Nurnabi,Mohammad Molla,Ashraful Islam
spellingShingle	Rahman,Mohammad Nahidur Bhowmick,Rina Rani Nurnabi,Mohammad Molla,Ashraful Islam SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
author_facet	Rahman,Mohammad Nahidur Bhowmick,Rina Rani Nurnabi,Mohammad Molla,Ashraful Islam
author_sort	Rahman,Mohammad Nahidur
title	SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
title_short	SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
title_full	SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
title_fullStr	SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
title_full_unstemmed	SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO
title_sort	synthesis and characterization of an amidoxime compound with benzimidazole moiety and ph sensing behavior under basic condition in methanol and dmso
publisher	Sociedad Chilena de Química
publishDate	2018
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304047
work_keys_str_mv	AT rahmanmohammadnahidur synthesisandcharacterizationofanamidoximecompoundwithbenzimidazolemoietyandphsensingbehaviorunderbasicconditioninmethanolanddmso AT bhowmickrinarani synthesisandcharacterizationofanamidoximecompoundwithbenzimidazolemoietyandphsensingbehaviorunderbasicconditioninmethanolanddmso AT nurnabimohammad synthesisandcharacterizationofanamidoximecompoundwithbenzimidazolemoietyandphsensingbehaviorunderbasicconditioninmethanolanddmso AT mollaashrafulislam synthesisandcharacterizationofanamidoximecompoundwithbenzimidazolemoietyandphsensingbehaviorunderbasicconditioninmethanolanddmso
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SYNTHESIS AND CHARACTERIZATION OF AN AMIDOXIME COMPOUND WITH BENZIMIDAZOLE MOIETY AND PH SENSING BEHAVIOR UNDER BASIC CONDITION IN METHANOL AND DMSO

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