SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION

ABSTRACT A novel 1- naphthalene sulfonic acid (1-NS) molecularly imprinted polymer (MlP)-coated stir bar for sorptive extraction of four naphthalene sulfonates (NSs) from seawater samples was prepared. 1-NS was applied as template molecule. The extraction conditions, including pH, the absorption and...

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Autores principales:	Hashemi,Sayyed Hossein, Kaykhaii,Massoud, Tabehzar,Fatemeh
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2018
Materias:	Naphthalene sulfonates molecularly imprinted polymer coated stir bar (MIPSB) Seawater Chabahar Bay
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304057
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spelling	oai:scielo:S0717-970720180003040572018-10-03SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTIONHashemi,Sayyed HosseinKaykhaii,MassoudTabehzar,Fatemeh Naphthalene sulfonates molecularly imprinted polymer coated stir bar (MIPSB) Seawater Chabahar Bay ABSTRACT A novel 1- naphthalene sulfonic acid (1-NS) molecularly imprinted polymer (MlP)-coated stir bar for sorptive extraction of four naphthalene sulfonates (NSs) from seawater samples was prepared. 1-NS was applied as template molecule. The extraction conditions, including pH, the absorption and desorption times, stirring speed, amount of NaCl and temperature were optimized and the optimum conditions were established as: the absorption and desorption times were fixed respectively at 10 and 15 min, stirring speed was 600 rpm, pH was adjusted to 4.1, amount of NaCl was 1 mol L−1 and extraction process was performed at a temperature of 45 °C. The linear ranges were 5-250 μg L−1 for 3, 6-NDS-1-OH (1-naphthol-3,6-disulfonic acid), 2-NS (2-naphthalene sulfonate) and 1-NS and 10-250 μg L−1 for 5-NH2-1-NS (5-Amino-1-naphthalenesulfonic acid). The detection limits were within the range of 1.20- 2.97 μg L−1. Under the optimum conditions, with the enrichment factor of the NSs were 27, 10, 14 and 7 fold for 2-NS, 1-NS, 3, 6- NDS-1-OH and 5-NH2-1-NS respectively. The RSDs was within 1-9.4%. The method is very suitable for the determination of naphthalene sulfonates (NSs) in seawater samples.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.3 20182018-01-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304057en10.4067/s0717-97072018000304057
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Naphthalene sulfonates molecularly imprinted polymer coated stir bar (MIPSB) Seawater Chabahar Bay
spellingShingle	Naphthalene sulfonates molecularly imprinted polymer coated stir bar (MIPSB) Seawater Chabahar Bay Hashemi,Sayyed Hossein Kaykhaii,Massoud Tabehzar,Fatemeh SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
description	ABSTRACT A novel 1- naphthalene sulfonic acid (1-NS) molecularly imprinted polymer (MlP)-coated stir bar for sorptive extraction of four naphthalene sulfonates (NSs) from seawater samples was prepared. 1-NS was applied as template molecule. The extraction conditions, including pH, the absorption and desorption times, stirring speed, amount of NaCl and temperature were optimized and the optimum conditions were established as: the absorption and desorption times were fixed respectively at 10 and 15 min, stirring speed was 600 rpm, pH was adjusted to 4.1, amount of NaCl was 1 mol L−1 and extraction process was performed at a temperature of 45 °C. The linear ranges were 5-250 μg L−1 for 3, 6-NDS-1-OH (1-naphthol-3,6-disulfonic acid), 2-NS (2-naphthalene sulfonate) and 1-NS and 10-250 μg L−1 for 5-NH2-1-NS (5-Amino-1-naphthalenesulfonic acid). The detection limits were within the range of 1.20- 2.97 μg L−1. Under the optimum conditions, with the enrichment factor of the NSs were 27, 10, 14 and 7 fold for 2-NS, 1-NS, 3, 6- NDS-1-OH and 5-NH2-1-NS respectively. The RSDs was within 1-9.4%. The method is very suitable for the determination of naphthalene sulfonates (NSs) in seawater samples.
author	Hashemi,Sayyed Hossein Kaykhaii,Massoud Tabehzar,Fatemeh
author_facet	Hashemi,Sayyed Hossein Kaykhaii,Massoud Tabehzar,Fatemeh
author_sort	Hashemi,Sayyed Hossein
title	SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
title_short	SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
title_full	SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
title_fullStr	SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
title_full_unstemmed	SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION
title_sort	spectrophotometric determination of four naphthalene sulfonates in seawater after their molecularly imprinted stir bar sorptive extraction
publisher	Sociedad Chilena de Química
publishDate	2018
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000304057
work_keys_str_mv	AT hashemisayyedhossein spectrophotometricdeterminationoffournaphthalenesulfonatesinseawateraftertheirmolecularlyimprintedstirbarsorptiveextraction AT kaykhaiimassoud spectrophotometricdeterminationoffournaphthalenesulfonatesinseawateraftertheirmolecularlyimprintedstirbarsorptiveextraction AT tabehzarfatemeh spectrophotometricdeterminationoffournaphthalenesulfonatesinseawateraftertheirmolecularlyimprintedstirbarsorptiveextraction
_version_	1714200927906299904

SPECTROPHOTOMETRIC DETERMINATION OF FOUR NAPHTHALENE SULFONATES IN SEAWATER AFTER THEIR MOLECULARLY IMPRINTED STIR BAR SORPTIVE EXTRACTION

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