Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM

ABSTRACT Mononuclear manganese complexes of dihydrazone derived from the condensation of oxaloyldihydrazide with 2-hydroxynaphthaldehyde and 2-methoxybenzaldehyde have been synthesized. The hydrazone Schiff base ligands and their chelates were characterized on the basis of their elemental analyses,...

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Autores principales:	Ahmed,Ayman H., Hassan,A.M., Gumaa,Hosni A., Mohamed,Bassem H., Eraky,Ahmed M.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2018
Materias:	Metal complexes Hydrazones Structure elucidation Corrosion
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000404180
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spelling	oai:scielo:S0717-970720180004041802019-02-07Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUMAhmed,Ayman H.Hassan,A.M.Gumaa,Hosni A.Mohamed,Bassem H.Eraky,Ahmed M. Metal complexes Hydrazones Structure elucidation Corrosion ABSTRACT Mononuclear manganese complexes of dihydrazone derived from the condensation of oxaloyldihydrazide with 2-hydroxynaphthaldehyde and 2-methoxybenzaldehyde have been synthesized. The hydrazone Schiff base ligands and their chelates were characterized on the basis of their elemental analyses, spectral (UV-Vis., IR, mass, 1H/13C NMR), magnetism, ESR and thermal (TGA) measurements. The dihydrazone has been suggested to coordinate to the metal center in bi-dentate manner forming 1:1[M:L] complex. The complexes are suggested to have tetrahedral/octahedral stereochemistry. Optical transmission spectra were recorded in the range 190–2100 nm and optical band gap energy was determined. The band gap energy (Eg) for all separated compounds lies in the range of semiconductors. On the other hand, the inhibition and adsorptive properties of the ligands for the corrosion of aluminum in 1 M HCl solutions were studied using traditional weight loss measurements. The results revealed that bis(2-methoxy-benzaldehyde)oxaloyldihydrazone has a greater inhibition than bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone. The adsorption of the inhibitors on metal surface was found to be spontaneous first order reaction and consistent well with the mechanism of physical adsorption. The adsorption data fitted well to Freundlich, Langmuir and Frumkin adsorption isotherms.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.63 n.4 20182018-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000404180en10.4067/S0717-97072018000404180
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Metal complexes Hydrazones Structure elucidation Corrosion
spellingShingle	Metal complexes Hydrazones Structure elucidation Corrosion Ahmed,Ayman H. Hassan,A.M. Gumaa,Hosni A. Mohamed,Bassem H. Eraky,Ahmed M. Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
description	ABSTRACT Mononuclear manganese complexes of dihydrazone derived from the condensation of oxaloyldihydrazide with 2-hydroxynaphthaldehyde and 2-methoxybenzaldehyde have been synthesized. The hydrazone Schiff base ligands and their chelates were characterized on the basis of their elemental analyses, spectral (UV-Vis., IR, mass, 1H/13C NMR), magnetism, ESR and thermal (TGA) measurements. The dihydrazone has been suggested to coordinate to the metal center in bi-dentate manner forming 1:1[M:L] complex. The complexes are suggested to have tetrahedral/octahedral stereochemistry. Optical transmission spectra were recorded in the range 190–2100 nm and optical band gap energy was determined. The band gap energy (Eg) for all separated compounds lies in the range of semiconductors. On the other hand, the inhibition and adsorptive properties of the ligands for the corrosion of aluminum in 1 M HCl solutions were studied using traditional weight loss measurements. The results revealed that bis(2-methoxy-benzaldehyde)oxaloyldihydrazone has a greater inhibition than bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone. The adsorption of the inhibitors on metal surface was found to be spontaneous first order reaction and consistent well with the mechanism of physical adsorption. The adsorption data fitted well to Freundlich, Langmuir and Frumkin adsorption isotherms.
author	Ahmed,Ayman H. Hassan,A.M. Gumaa,Hosni A. Mohamed,Bassem H. Eraky,Ahmed M.
author_facet	Ahmed,Ayman H. Hassan,A.M. Gumaa,Hosni A. Mohamed,Bassem H. Eraky,Ahmed M.
author_sort	Ahmed,Ayman H.
title	Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
title_short	Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
title_full	Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
title_fullStr	Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
title_full_unstemmed	Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM
title_sort	mn2+-complexes of n,o-dihydrazone: structural studies, indirect band gap energy and corrosion inhibition on aluminum in acidic medium
publisher	Sociedad Chilena de Química
publishDate	2018
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072018000404180
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_version_	1714200931156885504

Mn2+-COMPLEXES OF N,O-DIHYDRAZONE: STRUCTURAL STUDIES, INDIRECT BAND GAP ENERGY AND CORROSION INHIBITION ON ALUMINUM IN ACIDIC MEDIUM

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