CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

ABSTRACT In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several...

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Autores principales:	Maharramov,Abel M., Duruskari,Gulnara SH., Mammadova,Gunay Z., Khalilov,Ali N., Aslanova,Javahir M., Cisterna,Jonathan, Cárdenas,Alejandro, Brito,Iván
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2019
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072019000204441
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spelling	oai:scielo:S0717-970720190002044412019-10-11CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDEMaharramov,Abel M.Duruskari,Gulnara SH.Mammadova,Gunay Z.Khalilov,Ali N.Aslanova,Javahir M.Cisterna,JonathanCárdenas,AlejandroBrito,IvánABSTRACT In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H⋯F, H⋯π and H⋯Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.64 n.2 20192019-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072019000204441en10.4067/S0717-97072019000204441
institution	Scielo Chile
collection	Scielo Chile
language	English
description	ABSTRACT In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H⋯F, H⋯π and H⋯Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.
author	Maharramov,Abel M. Duruskari,Gulnara SH. Mammadova,Gunay Z. Khalilov,Ali N. Aslanova,Javahir M. Cisterna,Jonathan Cárdenas,Alejandro Brito,Iván
spellingShingle	Maharramov,Abel M. Duruskari,Gulnara SH. Mammadova,Gunay Z. Khalilov,Ali N. Aslanova,Javahir M. Cisterna,Jonathan Cárdenas,Alejandro Brito,Iván CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
author_facet	Maharramov,Abel M. Duruskari,Gulnara SH. Mammadova,Gunay Z. Khalilov,Ali N. Aslanova,Javahir M. Cisterna,Jonathan Cárdenas,Alejandro Brito,Iván
author_sort	Maharramov,Abel M.
title	CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
title_short	CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
title_full	CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
title_fullStr	CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
title_full_unstemmed	CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
title_sort	crystal structure and hirshfeld surface analysis of (e)-5-phenyl-3-((4-(trifluoromethyl)benzylidene)amino)thiazolidin-2-iminium bromide
publisher	Sociedad Chilena de Química
publishDate	2019
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072019000204441
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CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE

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