MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION

MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION

ABSTRACT Totally irreversible electro-oxidation of dissolved reactant that is inhibited by the formation of oxide on the electrode surface is analysed theoretically. In the reverse, cathodic branch of staircase cyclic voltammogram these two parallel reactions exhibit both cathodic minimum and anodic...

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Autores principales: Lovrić,Milivoj, Komorsky-Lovrić,Šebojka
Lenguaje:English
Publicado: Sociedad Chilena de Química 2020
Materias:
Voltammetry
Inhibition
Oxide
Simulation
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000104661
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spelling oai:scielo:S0717-970720200001046612020-04-16MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATIONLovrić,MilivojKomorsky-Lovrić,Šebojka Voltammetry Inhibition Oxide Simulation ABSTRACT Totally irreversible electro-oxidation of dissolved reactant that is inhibited by the formation of oxide on the electrode surface is analysed theoretically. In the reverse, cathodic branch of staircase cyclic voltammogram these two parallel reactions exhibit both cathodic minimum and anodic maximum. The potentials of these extremes depend on the kinetics of oxide formation.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.65 n.1 20202020-03-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000104661en10.4067/S0717-97072020000104661
institution Scielo Chile
collection Scielo Chile
language English
topic Voltammetry
Inhibition
Oxide
Simulation
spellingShingle Voltammetry
Inhibition
Oxide
Simulation
Lovrić,Milivoj
Komorsky-Lovrić,Šebojka
MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
description ABSTRACT Totally irreversible electro-oxidation of dissolved reactant that is inhibited by the formation of oxide on the electrode surface is analysed theoretically. In the reverse, cathodic branch of staircase cyclic voltammogram these two parallel reactions exhibit both cathodic minimum and anodic maximum. The potentials of these extremes depend on the kinetics of oxide formation.
author Lovrić,Milivoj
Komorsky-Lovrić,Šebojka
author_facet Lovrić,Milivoj
Komorsky-Lovrić,Šebojka
author_sort Lovrić,Milivoj
title MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
title_short MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
title_full MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
title_fullStr MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
title_full_unstemmed MODELLING REVERSIBLE INHIBITION OF IRREVERSIBLE ELECTRO-OXIDATION
title_sort modelling reversible inhibition of irreversible electro-oxidation
publisher Sociedad Chilena de Química
publishDate 2020
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000104661
work_keys_str_mv AT lovri263milivoj modellingreversibleinhibitionofirreversibleelectrooxidation
AT komorskylovri263352ebojka modellingreversibleinhibitionofirreversibleelectrooxidation
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