PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS

ABSTRACT In the present study, to enhance removal of quinoline contaminants using natural active component, vanillin was loaded onto the MCM-41 (Mobile Component Material) nanoparticles in a simple way. The product was divided into two parts, which were improved by Copper(I) and Copper(II) salts. Pr...

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Autores principales:	Kamani,Mina, Fazaeli,Reza, Arjmand,Mehdi, Hossein Ghorbani,Mohammad
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2020
Materias:	Catalytic Properties Quinoline Response Surface Methodology Vanillin/MCM-41
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000204833
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spelling	oai:scielo:S0717-970720200002048332020-08-14PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTSKamani,MinaFazaeli,RezaArjmand,MehdiHossein Ghorbani,Mohammad Catalytic Properties Quinoline Response Surface Methodology Vanillin/MCM-41 ABSTRACT In the present study, to enhance removal of quinoline contaminants using natural active component, vanillin was loaded onto the MCM-41 (Mobile Component Material) nanoparticles in a simple way. The product was divided into two parts, which were improved by Copper(I) and Copper(II) salts. Promoted synthetic nanocatalysts (Cu(I)/Van./MCM-41, and Cu(II)/Van./MCM-41) were characterized using X-Ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy-Dispersive X-Ray Spectroscopy (EDS), Mapping, Fourier-Transform Infrared Spectroscopy (FTIR), and BET/BJH (Brunauer-Emmett-Teller (BET) and Barret-Joyner-Halenda (BJH)) techniques. To reach optimal conditions, experimental design was performed using Response Surface Methodology (RSM). The experiments were done with the aid of nanocomposites, in presence of ultraviolet radiation without any auxiliary oxidants. Degradation percentages were measured by an Ultraviolet (UV) spectrophotometer. The products were identified using Gas Chromatography–Mass (GC-Mass) technique, and some mechanisms for quinoline removal were proposed. The results indicated that Cu (I) showed better performance in enhanced removal of quinoline than Cu(II).info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.65 n.2 20202020-06-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000204833en10.4067/S0717-97072020000204833
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Catalytic Properties Quinoline Response Surface Methodology Vanillin/MCM-41
spellingShingle	Catalytic Properties Quinoline Response Surface Methodology Vanillin/MCM-41 Kamani,Mina Fazaeli,Reza Arjmand,Mehdi Hossein Ghorbani,Mohammad PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
description	ABSTRACT In the present study, to enhance removal of quinoline contaminants using natural active component, vanillin was loaded onto the MCM-41 (Mobile Component Material) nanoparticles in a simple way. The product was divided into two parts, which were improved by Copper(I) and Copper(II) salts. Promoted synthetic nanocatalysts (Cu(I)/Van./MCM-41, and Cu(II)/Van./MCM-41) were characterized using X-Ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy-Dispersive X-Ray Spectroscopy (EDS), Mapping, Fourier-Transform Infrared Spectroscopy (FTIR), and BET/BJH (Brunauer-Emmett-Teller (BET) and Barret-Joyner-Halenda (BJH)) techniques. To reach optimal conditions, experimental design was performed using Response Surface Methodology (RSM). The experiments were done with the aid of nanocomposites, in presence of ultraviolet radiation without any auxiliary oxidants. Degradation percentages were measured by an Ultraviolet (UV) spectrophotometer. The products were identified using Gas Chromatography–Mass (GC-Mass) technique, and some mechanisms for quinoline removal were proposed. The results indicated that Cu (I) showed better performance in enhanced removal of quinoline than Cu(II).
author	Kamani,Mina Fazaeli,Reza Arjmand,Mehdi Hossein Ghorbani,Mohammad
author_facet	Kamani,Mina Fazaeli,Reza Arjmand,Mehdi Hossein Ghorbani,Mohammad
author_sort	Kamani,Mina
title	PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
title_short	PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
title_full	PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
title_fullStr	PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
title_full_unstemmed	PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS
title_sort	promotion of catalytic properties of vanillin loaded mcm-41 by cu(i) and cu(ii) for enhanced removal of quinoline contaminants
publisher	Sociedad Chilena de Química
publishDate	2020
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000204833
work_keys_str_mv	AT kamanimina promotionofcatalyticpropertiesofvanillinloadedmcm41bycuiandcuiiforenhancedremovalofquinolinecontaminants AT fazaelireza promotionofcatalyticpropertiesofvanillinloadedmcm41bycuiandcuiiforenhancedremovalofquinolinecontaminants AT arjmandmehdi promotionofcatalyticpropertiesofvanillinloadedmcm41bycuiandcuiiforenhancedremovalofquinolinecontaminants AT hosseinghorbanimohammad promotionofcatalyticpropertiesofvanillinloadedmcm41bycuiandcuiiforenhancedremovalofquinolinecontaminants
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PROMOTION OF CATALYTIC PROPERTIES OF VANILLIN LOADED MCM-41 BY CU(I) AND CU(II) FOR ENHANCED REMOVAL OF QUINOLINE CONTAMINANTS

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