NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence...
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Sociedad Chilena de Química
2020
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oai:scielo:S0717-970720200003048532020-10-09NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREASMiar,MarziehPourshamsian,KhalilShiroudi,AbolfazlHatamjafari,FarhadOliaey,Ahmad Reza 3-aryl benzo[d]thiazole-2(3H)-imines Diazonium salt N- acyl-N’-aryl thiourea ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence of sodium tert-butoxide as strong base. Finally, it resulted in the production of the desired products with a moderate yield. The chemical structures of these synthesized compounds were confirmed by various physico-chemical methods viz. FT-IR, 1H-NMR, 13C-NMR, and elemental analysis.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.65 n.3 20202020-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000304853en10.4067/s0717-97072020000204853 |
institution |
Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
3-aryl benzo[d]thiazole-2(3H)-imines Diazonium salt N- acyl-N’-aryl thiourea |
spellingShingle |
3-aryl benzo[d]thiazole-2(3H)-imines Diazonium salt N- acyl-N’-aryl thiourea Miar,Marzieh Pourshamsian,Khalil Shiroudi,Abolfazl Hatamjafari,Farhad Oliaey,Ahmad Reza NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
description |
ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence of sodium tert-butoxide as strong base. Finally, it resulted in the production of the desired products with a moderate yield. The chemical structures of these synthesized compounds were confirmed by various physico-chemical methods viz. FT-IR, 1H-NMR, 13C-NMR, and elemental analysis. |
author |
Miar,Marzieh Pourshamsian,Khalil Shiroudi,Abolfazl Hatamjafari,Farhad Oliaey,Ahmad Reza |
author_facet |
Miar,Marzieh Pourshamsian,Khalil Shiroudi,Abolfazl Hatamjafari,Farhad Oliaey,Ahmad Reza |
author_sort |
Miar,Marzieh |
title |
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
title_short |
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
title_full |
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
title_fullStr |
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
title_full_unstemmed |
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS |
title_sort |
new route for the syntheses of some novel derivatives of 3-aryl benzo[d] thiazole-2(3h)-imine from high substituted thioureas |
publisher |
Sociedad Chilena de Química |
publishDate |
2020 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000304853 |
work_keys_str_mv |
AT miarmarzieh newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas AT pourshamsiankhalil newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas AT shiroudiabolfazl newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas AT hatamjafarifarhad newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas AT oliaeyahmadreza newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas |
_version_ |
1714200948948074496 |