NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS

ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence...

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Autores principales: Miar,Marzieh, Pourshamsian,Khalil, Shiroudi,Abolfazl, Hatamjafari,Farhad, Oliaey,Ahmad Reza
Lenguaje:English
Publicado: Sociedad Chilena de Química 2020
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000304853
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spelling oai:scielo:S0717-970720200003048532020-10-09NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREASMiar,MarziehPourshamsian,KhalilShiroudi,AbolfazlHatamjafari,FarhadOliaey,Ahmad Reza 3-aryl benzo[d]thiazole-2(3H)-imines Diazonium salt N- acyl-N’-aryl thiourea ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence of sodium tert-butoxide as strong base. Finally, it resulted in the production of the desired products with a moderate yield. The chemical structures of these synthesized compounds were confirmed by various physico-chemical methods viz. FT-IR, 1H-NMR, 13C-NMR, and elemental analysis.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.65 n.3 20202020-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000304853en10.4067/s0717-97072020000204853
institution Scielo Chile
collection Scielo Chile
language English
topic 3-aryl benzo[d]thiazole-2(3H)-imines
Diazonium salt
N- acyl-N’-aryl thiourea
spellingShingle 3-aryl benzo[d]thiazole-2(3H)-imines
Diazonium salt
N- acyl-N’-aryl thiourea
Miar,Marzieh
Pourshamsian,Khalil
Shiroudi,Abolfazl
Hatamjafari,Farhad
Oliaey,Ahmad Reza
NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
description ABSTRACT We have developed herein a new approach to the diverse synthesis of novel derivatives of 3-aryl benzo[d]thiazole-2(3H)-imines (3a–g), by a two-component reaction between diazonium salt (2) and various synthesized N-acyl-N’-aryl thioureas (1a–g), in the presence of sodium tert-butoxide as strong base. Finally, it resulted in the production of the desired products with a moderate yield. The chemical structures of these synthesized compounds were confirmed by various physico-chemical methods viz. FT-IR, 1H-NMR, 13C-NMR, and elemental analysis.
author Miar,Marzieh
Pourshamsian,Khalil
Shiroudi,Abolfazl
Hatamjafari,Farhad
Oliaey,Ahmad Reza
author_facet Miar,Marzieh
Pourshamsian,Khalil
Shiroudi,Abolfazl
Hatamjafari,Farhad
Oliaey,Ahmad Reza
author_sort Miar,Marzieh
title NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
title_short NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
title_full NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
title_fullStr NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
title_full_unstemmed NEW ROUTE FOR THE SYNTHESES OF SOME NOVEL DERIVATIVES OF 3-ARYL BENZO[d] THIAZOLE-2(3H)-IMINE FROM HIGH SUBSTITUTED THIOUREAS
title_sort new route for the syntheses of some novel derivatives of 3-aryl benzo[d] thiazole-2(3h)-imine from high substituted thioureas
publisher Sociedad Chilena de Química
publishDate 2020
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072020000304853
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AT pourshamsiankhalil newrouteforthesynthesesofsomenovelderivativesof3arylbenzodthiazole23himinefromhighsubstitutedthioureas
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