Wood thermodegradation: experimental analysis and modeling of mass loss kinetics

Wood heat treatment is an attractive alternative to improve decay resistance of low natural durability of wood species. Decay resistance is strongly correlated to thermal degradation of wood cell wall components. Some recent studies proposed the use of wood mass loss during the heat treatment as a v...

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Autores principales: Pétrissans,A, Younsi,R, Chaouch,M, Gérardin,P, Pétrissans,M
Lenguaje:English
Publicado: Universidad del Bío-Bío 2014
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2014000200001
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spelling oai:scielo:S0718-221X20140002000012014-05-13Wood thermodegradation: experimental analysis and modeling of mass loss kineticsPétrissans,AYounsi,RChaouch,MGérardin,PPétrissans,M Heat treatment modeling reaction kinetics thermodegradation wood Wood heat treatment is an attractive alternative to improve decay resistance of low natural durability of wood species. Decay resistance is strongly correlated to thermal degradation of wood cell wall components. Some recent studies proposed the use of wood mass loss during the heat treatment as a valuable marker to predict final properties of the material (Hakkou et al. 2006, Welzbacher et al. 2007). In this study, heat treatment was carried out in a relatively low temperature (230˚C). Mass loss kinetics was studied using equipment, specially conceived to measure sample’s mass during the thermal treatment. Laboratory experiments were performed for heating rates of 1˚C min-1. Mathematical model for kinetics of pyrolysis process was used and validated. During the pyrolysis of dry wood samples under inert atmosphere, measurements of temperature distribution and dynamic weight loss were performed. Five different wood species Fagus sylvatica (Beech), Populus nigra (Poplar), Fraxinus excelsior (Ash), Pinus sylvestris (Pine) and Abies pectinata (Silver Fir) were investigated. The unsteady-state mathematical model equations were solved numerically using the commercial package Femlab 2.0. A detailed discussion of the computational model and the solution algorithm is given. The validity of different model assumptions was analyzed. Experimental results were compared with those calculated by the model. Acceptable agreement was achieved.info:eu-repo/semantics/openAccessUniversidad del Bío-BíoMaderas. Ciencia y tecnología v.16 n.2 20142014-05-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2014000200001en
institution Scielo Chile
collection Scielo Chile
language English
topic Heat treatment
modeling
reaction kinetics
thermodegradation
wood
spellingShingle Heat treatment
modeling
reaction kinetics
thermodegradation
wood
Pétrissans,A
Younsi,R
Chaouch,M
Gérardin,P
Pétrissans,M
Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
description Wood heat treatment is an attractive alternative to improve decay resistance of low natural durability of wood species. Decay resistance is strongly correlated to thermal degradation of wood cell wall components. Some recent studies proposed the use of wood mass loss during the heat treatment as a valuable marker to predict final properties of the material (Hakkou et al. 2006, Welzbacher et al. 2007). In this study, heat treatment was carried out in a relatively low temperature (230˚C). Mass loss kinetics was studied using equipment, specially conceived to measure sample’s mass during the thermal treatment. Laboratory experiments were performed for heating rates of 1˚C min-1. Mathematical model for kinetics of pyrolysis process was used and validated. During the pyrolysis of dry wood samples under inert atmosphere, measurements of temperature distribution and dynamic weight loss were performed. Five different wood species Fagus sylvatica (Beech), Populus nigra (Poplar), Fraxinus excelsior (Ash), Pinus sylvestris (Pine) and Abies pectinata (Silver Fir) were investigated. The unsteady-state mathematical model equations were solved numerically using the commercial package Femlab 2.0. A detailed discussion of the computational model and the solution algorithm is given. The validity of different model assumptions was analyzed. Experimental results were compared with those calculated by the model. Acceptable agreement was achieved.
author Pétrissans,A
Younsi,R
Chaouch,M
Gérardin,P
Pétrissans,M
author_facet Pétrissans,A
Younsi,R
Chaouch,M
Gérardin,P
Pétrissans,M
author_sort Pétrissans,A
title Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
title_short Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
title_full Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
title_fullStr Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
title_full_unstemmed Wood thermodegradation: experimental analysis and modeling of mass loss kinetics
title_sort wood thermodegradation: experimental analysis and modeling of mass loss kinetics
publisher Universidad del Bío-Bío
publishDate 2014
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2014000200001
work_keys_str_mv AT petrissansa woodthermodegradationexperimentalanalysisandmodelingofmasslosskinetics
AT younsir woodthermodegradationexperimentalanalysisandmodelingofmasslosskinetics
AT chaouchm woodthermodegradationexperimentalanalysisandmodelingofmasslosskinetics
AT gerardinp woodthermodegradationexperimentalanalysisandmodelingofmasslosskinetics
AT petrissansm woodthermodegradationexperimentalanalysisandmodelingofmasslosskinetics
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