Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood

This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxid...

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Autores principales: Xavier,Lucía, Freire,María Sonia, Vidal-Tato,Isabel, González-Álvarez,Julia
Lenguaje:English
Publicado: Universidad del Bío-Bío 2015
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2015000200012
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spelling oai:scielo:S0718-221X20150002000122015-06-17Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus woodXavier,LucíaFreire,María SoniaVidal-Tato,IsabelGonzález-Álvarez,Julia Aqueous two-phase systems biomass wastes Eucalyptus wood natural antioxidants polyethylene glycol sodium citrate This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxidants for applications including cosmetics, pharmaceuticals, food additives and other industrial applications. The influence of the tie line length (TLL) (26,1-46,1%), extraction temperature (25-65ºC), extraction time (90-390 min) and phase settlement time (1-8 h) were studied. Phenolic compounds were concentrated preferentially in the PEG-rich phase. A partition coefficient of 38 and a total phenols yield of 1,29 mg gallic acid equivalent/100 mg wood dry basis were obtained under the operational conditions selected: TLL, 46,1%, temperature 65ºC, extraction time 90 min and settlement time 1 h. Analysis of the extracts by RP-HPLC-ESI-TOF confirmed the presence of various phenolic compounds with demonstrated antioxidant activity: monogalloyl glucose, (-)-gallic acid, ellagic acid and quercetin 3-O-rhamnoside.info:eu-repo/semantics/openAccessUniversidad del Bío-BíoMaderas. Ciencia y tecnología v.17 n.2 20152015-04-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2015000200012en10.4067/S0718-221X2015005000032
institution Scielo Chile
collection Scielo Chile
language English
topic Aqueous two-phase systems
biomass wastes
Eucalyptus wood
natural antioxidants
polyethylene glycol
sodium citrate
spellingShingle Aqueous two-phase systems
biomass wastes
Eucalyptus wood
natural antioxidants
polyethylene glycol
sodium citrate
Xavier,Lucía
Freire,María Sonia
Vidal-Tato,Isabel
González-Álvarez,Julia
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
description This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxidants for applications including cosmetics, pharmaceuticals, food additives and other industrial applications. The influence of the tie line length (TLL) (26,1-46,1%), extraction temperature (25-65ºC), extraction time (90-390 min) and phase settlement time (1-8 h) were studied. Phenolic compounds were concentrated preferentially in the PEG-rich phase. A partition coefficient of 38 and a total phenols yield of 1,29 mg gallic acid equivalent/100 mg wood dry basis were obtained under the operational conditions selected: TLL, 46,1%, temperature 65ºC, extraction time 90 min and settlement time 1 h. Analysis of the extracts by RP-HPLC-ESI-TOF confirmed the presence of various phenolic compounds with demonstrated antioxidant activity: monogalloyl glucose, (-)-gallic acid, ellagic acid and quercetin 3-O-rhamnoside.
author Xavier,Lucía
Freire,María Sonia
Vidal-Tato,Isabel
González-Álvarez,Julia
author_facet Xavier,Lucía
Freire,María Sonia
Vidal-Tato,Isabel
González-Álvarez,Julia
author_sort Xavier,Lucía
title Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
title_short Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
title_full Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
title_fullStr Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
title_full_unstemmed Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
title_sort application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from eucalyptus wood
publisher Universidad del Bío-Bío
publishDate 2015
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2015000200012
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AT freiremariasonia applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood
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AT gonzalezalvarezjulia applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood
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