Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood
This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxid...
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Universidad del Bío-Bío
2015
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oai:scielo:S0718-221X20150002000122015-06-17Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus woodXavier,LucíaFreire,María SoniaVidal-Tato,IsabelGonzález-Álvarez,Julia Aqueous two-phase systems biomass wastes Eucalyptus wood natural antioxidants polyethylene glycol sodium citrate This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxidants for applications including cosmetics, pharmaceuticals, food additives and other industrial applications. The influence of the tie line length (TLL) (26,1-46,1%), extraction temperature (25-65ºC), extraction time (90-390 min) and phase settlement time (1-8 h) were studied. Phenolic compounds were concentrated preferentially in the PEG-rich phase. A partition coefficient of 38 and a total phenols yield of 1,29 mg gallic acid equivalent/100 mg wood dry basis were obtained under the operational conditions selected: TLL, 46,1%, temperature 65ºC, extraction time 90 min and settlement time 1 h. Analysis of the extracts by RP-HPLC-ESI-TOF confirmed the presence of various phenolic compounds with demonstrated antioxidant activity: monogalloyl glucose, (-)-gallic acid, ellagic acid and quercetin 3-O-rhamnoside.info:eu-repo/semantics/openAccessUniversidad del Bío-BíoMaderas. Ciencia y tecnología v.17 n.2 20152015-04-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2015000200012en10.4067/S0718-221X2015005000032 |
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English |
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Aqueous two-phase systems biomass wastes Eucalyptus wood natural antioxidants polyethylene glycol sodium citrate |
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Aqueous two-phase systems biomass wastes Eucalyptus wood natural antioxidants polyethylene glycol sodium citrate Xavier,Lucía Freire,María Sonia Vidal-Tato,Isabel González-Álvarez,Julia Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
description |
This paper proposes an alternative way to intensify the exploitation of Eucalyptus wood wastes before valorisation for energy production. An aqueous two-phase system (ATPS) based on PEG 2000 and sodium citrate was investigated for the recovery of phenolic compounds that could act as natural antioxidants for applications including cosmetics, pharmaceuticals, food additives and other industrial applications. The influence of the tie line length (TLL) (26,1-46,1%), extraction temperature (25-65ºC), extraction time (90-390 min) and phase settlement time (1-8 h) were studied. Phenolic compounds were concentrated preferentially in the PEG-rich phase. A partition coefficient of 38 and a total phenols yield of 1,29 mg gallic acid equivalent/100 mg wood dry basis were obtained under the operational conditions selected: TLL, 46,1%, temperature 65ºC, extraction time 90 min and settlement time 1 h. Analysis of the extracts by RP-HPLC-ESI-TOF confirmed the presence of various phenolic compounds with demonstrated antioxidant activity: monogalloyl glucose, (-)-gallic acid, ellagic acid and quercetin 3-O-rhamnoside. |
author |
Xavier,Lucía Freire,María Sonia Vidal-Tato,Isabel González-Álvarez,Julia |
author_facet |
Xavier,Lucía Freire,María Sonia Vidal-Tato,Isabel González-Álvarez,Julia |
author_sort |
Xavier,Lucía |
title |
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
title_short |
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
title_full |
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
title_fullStr |
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
title_full_unstemmed |
Application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from Eucalyptus wood |
title_sort |
application of aqueous two phase systems based on polyethylene glycol and sodium citrate for the recovery of phenolic compounds from eucalyptus wood |
publisher |
Universidad del Bío-Bío |
publishDate |
2015 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2015000200012 |
work_keys_str_mv |
AT xavierlucia applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood AT freiremariasonia applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood AT vidaltatoisabel applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood AT gonzalezalvarezjulia applicationofaqueoustwophasesystemsbasedonpolyethyleneglycolandsodiumcitratefortherecoveryofphenoliccompoundsfromeucalyptuswood |
_version_ |
1714202601464004608 |