Color changes of wood from Pinus taeda and Schizolobium parahybum treated by in situ polymerization of methyl methacrylate using cross-linkers

The aim of this study was to evaluate the colorimetric properties of Pinus taeda and Schizolobium parahybum woods treated by in situ polymerization. The wood samples were impregnated in a vacuum/pressure system and polymerized in an oven at 90°C for 10h, using benzoyl peroxide at 1,5wt% as the catal...

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Autores principales: Mattos,Bruno D, Missio,André L, de Cademartori,Pedro H.G, Gatto,Darci A, Magalhães,Washington L.E
Lenguaje:English
Publicado: Universidad del Bío-Bío 2016
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-221X2016000100012
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Sumario:The aim of this study was to evaluate the colorimetric properties of Pinus taeda and Schizolobium parahybum woods treated by in situ polymerization. The wood samples were impregnated in a vacuum/pressure system and polymerized in an oven at 90°C for 10h, using benzoyl peroxide at 1,5wt% as the catalyst. The treatments were characterized using attenuated total reflectance infrared (ATR-IR) spectroscopy and weight percentage gain (WPG). The color evaluation was performed using CIEL*a*b* concepts, specular gloss, and UV-Visible spectrophotometry. Treated woods showed increases in band intensity related to polymers (1730, 1460 and 1145 cm-1), and WPG ranged from 39 to 164%, depending of the wood species and treatments. Lightness decreased, while the Chroma, gloss and the color coordinates increased. A darkening of the all treated samples was observed, and confirmed by the decrease in the reflectance intensity between 400 and 700 nm.