MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS
In soil environments, sorption/desorption reactions as well as chemical complexation with inorganic and organic ligands and redox reactions, both biotic and abiotic, are of great importance in controlling their bioavailability, leaching and toxicity. These reactions are affected by many factors such...
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Chilean Society of Soil Science / Sociedad Chilena de la Ciencia del Suelo
2010
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oai:scielo:S0718-951620100001000052010-12-22MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTSViolante,ACozzolino,VPerelomov,LCaporale,A.GPigna,M bioavailability heavy metals metalloid adsorption desorption chemical speciation In soil environments, sorption/desorption reactions as well as chemical complexation with inorganic and organic ligands and redox reactions, both biotic and abiotic, are of great importance in controlling their bioavailability, leaching and toxicity. These reactions are affected by many factors such as pH, nature of the sorbents, presence and concentration of organic and inorganic ligands, including humic and fulvic acid, root exudates, microbial metabolites and nutrients. In this review, we highlight the impact of physical, chemical, and biological interfacial interactions on bioavailability and mobility of metals and metalloids in soil. Special attention is devoted to: i) the sorption/desorption processes of metals and metalloids on/from soil components and soils; ii) their precipitation and reduction-oxidation reactions in solution and onto surfaces of soil components; iii) their chemical speciation, fractionation and bioavailability.info:eu-repo/semantics/openAccessChilean Society of Soil Science / Sociedad Chilena de la Ciencia del SueloJournal of soil science and plant nutrition v.10 n.3 20102010-07-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-95162010000100005en10.4067/S0718-95162010000100005 |
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Scielo Chile |
collection |
Scielo Chile |
language |
English |
topic |
bioavailability heavy metals metalloid adsorption desorption chemical speciation |
spellingShingle |
bioavailability heavy metals metalloid adsorption desorption chemical speciation Violante,A Cozzolino,V Perelomov,L Caporale,A.G Pigna,M MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
description |
In soil environments, sorption/desorption reactions as well as chemical complexation with inorganic and organic ligands and redox reactions, both biotic and abiotic, are of great importance in controlling their bioavailability, leaching and toxicity. These reactions are affected by many factors such as pH, nature of the sorbents, presence and concentration of organic and inorganic ligands, including humic and fulvic acid, root exudates, microbial metabolites and nutrients. In this review, we highlight the impact of physical, chemical, and biological interfacial interactions on bioavailability and mobility of metals and metalloids in soil. Special attention is devoted to: i) the sorption/desorption processes of metals and metalloids on/from soil components and soils; ii) their precipitation and reduction-oxidation reactions in solution and onto surfaces of soil components; iii) their chemical speciation, fractionation and bioavailability. |
author |
Violante,A Cozzolino,V Perelomov,L Caporale,A.G Pigna,M |
author_facet |
Violante,A Cozzolino,V Perelomov,L Caporale,A.G Pigna,M |
author_sort |
Violante,A |
title |
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
title_short |
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
title_full |
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
title_fullStr |
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
title_full_unstemmed |
MOBILITY AND BIOAVAILABILITY OF HEAVY METALS AND METALLOIDS IN SOIL ENVIRONMENTS |
title_sort |
mobility and bioavailability of heavy metals and metalloids in soil environments |
publisher |
Chilean Society of Soil Science / Sociedad Chilena de la Ciencia del Suelo |
publishDate |
2010 |
url |
http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-95162010000100005 |
work_keys_str_mv |
AT violantea mobilityandbioavailabilityofheavymetalsandmetalloidsinsoilenvironments AT cozzolinov mobilityandbioavailabilityofheavymetalsandmetalloidsinsoilenvironments AT perelomovl mobilityandbioavailabilityofheavymetalsandmetalloidsinsoilenvironments AT caporaleag mobilityandbioavailabilityofheavymetalsandmetalloidsinsoilenvironments AT pignam mobilityandbioavailabilityofheavymetalsandmetalloidsinsoilenvironments |
_version_ |
1714206414244675584 |