Copper-catalyzed methylative difunctionalization of alkenes

While the trifluoromethylative difunctionalization of unactivated alkenes has been largely explored, methylative difunctionalization remains underinvestigated. Here, the authors report copper-catalyzed alkoxy- and azido-methylation reactions of alkenes leading to important synthetic building blocks...

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Autores principales:	Xu Bao, Takayuki Yokoe, Tu M. Ha, Qian Wang, Jieping Zhu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/06a36734259d4f51981da412240aea26
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id	oai:doaj.org-article:06a36734259d4f51981da412240aea26
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spelling	oai:doaj.org-article:06a36734259d4f51981da412240aea262021-12-02T14:40:05ZCopper-catalyzed methylative difunctionalization of alkenes10.1038/s41467-018-06246-62041-1723https://doaj.org/article/06a36734259d4f51981da412240aea262018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06246-6https://doaj.org/toc/2041-1723While the trifluoromethylative difunctionalization of unactivated alkenes has been largely explored, methylative difunctionalization remains underinvestigated. Here, the authors report copper-catalyzed alkoxy- and azido-methylation reactions of alkenes leading to important synthetic building blocks and valuable O- and N-heterocycles.Xu BaoTakayuki YokoeTu M. HaQian WangJieping ZhuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xu Bao Takayuki Yokoe Tu M. Ha Qian Wang Jieping Zhu Copper-catalyzed methylative difunctionalization of alkenes
description	While the trifluoromethylative difunctionalization of unactivated alkenes has been largely explored, methylative difunctionalization remains underinvestigated. Here, the authors report copper-catalyzed alkoxy- and azido-methylation reactions of alkenes leading to important synthetic building blocks and valuable O- and N-heterocycles.
format	article
author	Xu Bao Takayuki Yokoe Tu M. Ha Qian Wang Jieping Zhu
author_facet	Xu Bao Takayuki Yokoe Tu M. Ha Qian Wang Jieping Zhu
author_sort	Xu Bao
title	Copper-catalyzed methylative difunctionalization of alkenes
title_short	Copper-catalyzed methylative difunctionalization of alkenes
title_full	Copper-catalyzed methylative difunctionalization of alkenes
title_fullStr	Copper-catalyzed methylative difunctionalization of alkenes
title_full_unstemmed	Copper-catalyzed methylative difunctionalization of alkenes
title_sort	copper-catalyzed methylative difunctionalization of alkenes
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/06a36734259d4f51981da412240aea26
work_keys_str_mv	AT xubao coppercatalyzedmethylativedifunctionalizationofalkenes AT takayukiyokoe coppercatalyzedmethylativedifunctionalizationofalkenes AT tumha coppercatalyzedmethylativedifunctionalizationofalkenes AT qianwang coppercatalyzedmethylativedifunctionalizationofalkenes AT jiepingzhu coppercatalyzedmethylativedifunctionalizationofalkenes
_version_	1718390396562702336

Copper-catalyzed methylative difunctionalization of alkenes

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