Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation

The development of thia-Baeyer-Villiger reactions has been elusive so far due to competitive oxidation of sulfoxides to sulfones. Here, the authors show a thia-Baeyer-Villiger-type oxidations converting dibenzothiophene derivatives into sulfinic esters with t-BuOOH and an iron catalyst under UV irra...

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Bibliographic Details
Main Authors: Xiaofeng Ma, Yazhou Liu, Le Du, Jingwei Zhou, István E. Markó
Format: article
Language:EN
Published: Nature Portfolio 2020
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Online Access:https://doaj.org/article/0881bbcf24ef42a386f84b034f98df3c
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