Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation

Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation

The development of thia-Baeyer-Villiger reactions has been elusive so far due to competitive oxidation of sulfoxides to sulfones. Here, the authors show a thia-Baeyer-Villiger-type oxidations converting dibenzothiophene derivatives into sulfinic esters with t-BuOOH and an iron catalyst under UV irra...

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Autores principales: Xiaofeng Ma, Yazhou Liu, Le Du, Jingwei Zhou, István E. Markó
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/0881bbcf24ef42a386f84b034f98df3c
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spelling oai:doaj.org-article:0881bbcf24ef42a386f84b034f98df3c2021-12-02T14:40:28ZPost-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation10.1038/s41467-020-14522-72041-1723https://doaj.org/article/0881bbcf24ef42a386f84b034f98df3c2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14522-7https://doaj.org/toc/2041-1723The development of thia-Baeyer-Villiger reactions has been elusive so far due to competitive oxidation of sulfoxides to sulfones. Here, the authors show a thia-Baeyer-Villiger-type oxidations converting dibenzothiophene derivatives into sulfinic esters with t-BuOOH and an iron catalyst under UV irradiation.Xiaofeng MaYazhou LiuLe DuJingwei ZhouIstván E. MarkóNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xiaofeng Ma
Yazhou Liu
Le Du
Jingwei Zhou
István E. Markó
Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
description The development of thia-Baeyer-Villiger reactions has been elusive so far due to competitive oxidation of sulfoxides to sulfones. Here, the authors show a thia-Baeyer-Villiger-type oxidations converting dibenzothiophene derivatives into sulfinic esters with t-BuOOH and an iron catalyst under UV irradiation.
format article
author Xiaofeng Ma
Yazhou Liu
Le Du
Jingwei Zhou
István E. Markó
author_facet Xiaofeng Ma
Yazhou Liu
Le Du
Jingwei Zhou
István E. Markó
author_sort Xiaofeng Ma
title Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
title_short Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
title_full Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
title_fullStr Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
title_full_unstemmed Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
title_sort post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-baeyer-villiger oxidation
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/0881bbcf24ef42a386f84b034f98df3c
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AT yazhouliu postfunctionalizationofdibenzothiophenetofunctionalizedbiphenylsviaaphotoinducedthiabaeyervilligeroxidation
AT ledu postfunctionalizationofdibenzothiophenetofunctionalizedbiphenylsviaaphotoinducedthiabaeyervilligeroxidation
AT jingweizhou postfunctionalizationofdibenzothiophenetofunctionalizedbiphenylsviaaphotoinducedthiabaeyervilligeroxidation
AT istvanemarko postfunctionalizationofdibenzothiophenetofunctionalizedbiphenylsviaaphotoinducedthiabaeyervilligeroxidation
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