Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

Conventional palladium-catalyzed Heck reactions rely on the addition of oxidants and may suffer from low selectivity. Here, the authors report a nickel-catalyzed oxidative Heck arylation driven by transfer hydrogenation of an acceptor olefin leading to high E/Z selectivity and regioselectivity.

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Autores principales: Honggui Lv, Huiying Kang, Biying Zhou, Xiaosong Xue, Keary M. Engle, Dongbing Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/0a69fa16efc2485ab05c9eb0586557ea
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