Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

Conventional palladium-catalyzed Heck reactions rely on the addition of oxidants and may suffer from low selectivity. Here, the authors report a nickel-catalyzed oxidative Heck arylation driven by transfer hydrogenation of an acceptor olefin leading to high E/Z selectivity and regioselectivity.

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Autores principales:	Honggui Lv, Huiying Kang, Biying Zhou, Xiaosong Xue, Keary M. Engle, Dongbing Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0a69fa16efc2485ab05c9eb0586557ea
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spelling	oai:doaj.org-article:0a69fa16efc2485ab05c9eb0586557ea2021-12-02T15:35:54ZNickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation10.1038/s41467-019-12949-12041-1723https://doaj.org/article/0a69fa16efc2485ab05c9eb0586557ea2019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12949-1https://doaj.org/toc/2041-1723Conventional palladium-catalyzed Heck reactions rely on the addition of oxidants and may suffer from low selectivity. Here, the authors report a nickel-catalyzed oxidative Heck arylation driven by transfer hydrogenation of an acceptor olefin leading to high E/Z selectivity and regioselectivity.Honggui LvHuiying KangBiying ZhouXiaosong XueKeary M. EngleDongbing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Honggui Lv Huiying Kang Biying Zhou Xiaosong Xue Keary M. Engle Dongbing Zhao Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
description	Conventional palladium-catalyzed Heck reactions rely on the addition of oxidants and may suffer from low selectivity. Here, the authors report a nickel-catalyzed oxidative Heck arylation driven by transfer hydrogenation of an acceptor olefin leading to high E/Z selectivity and regioselectivity.
format	article
author	Honggui Lv Huiying Kang Biying Zhou Xiaosong Xue Keary M. Engle Dongbing Zhao
author_facet	Honggui Lv Huiying Kang Biying Zhou Xiaosong Xue Keary M. Engle Dongbing Zhao
author_sort	Honggui Lv
title	Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
title_short	Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
title_full	Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
title_fullStr	Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
title_full_unstemmed	Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
title_sort	nickel-catalyzed intermolecular oxidative heck arylation driven by transfer hydrogenation
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/0a69fa16efc2485ab05c9eb0586557ea
work_keys_str_mv	AT hongguilv nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation AT huiyingkang nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation AT biyingzhou nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation AT xiaosongxue nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation AT kearymengle nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation AT dongbingzhao nickelcatalyzedintermolecularoxidativeheckarylationdrivenbytransferhydrogenation
_version_	1718386393127845888

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation

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