Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
Conventional palladium-catalyzed Heck reactions rely on the addition of oxidants and may suffer from low selectivity. Here, the authors report a nickel-catalyzed oxidative Heck arylation driven by transfer hydrogenation of an acceptor olefin leading to high E/Z selectivity and regioselectivity.
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Auteurs principaux: | Honggui Lv, Huiying Kang, Biying Zhou, Xiaosong Xue, Keary M. Engle, Dongbing Zhao |
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Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2019
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Sujets: | |
Accès en ligne: | https://doaj.org/article/0a69fa16efc2485ab05c9eb0586557ea |
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