A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts
Frustrated Lewis pairs can be thermally revived from classical Lewis adducts, but the mechanism by which this occurs is not well understood. Here a combined experimental and theoretical study supports a pathway mediated by boron-jumping and dynamic conformational isomerization.
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| Autores principales: | , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/0b521bf3868344fdb2c03dfdeec5ed9f |
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