A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts
Frustrated Lewis pairs can be thermally revived from classical Lewis adducts, but the mechanism by which this occurs is not well understood. Here a combined experimental and theoretical study supports a pathway mediated by boron-jumping and dynamic conformational isomerization.
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Nature Portfolio
2021
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oai:doaj.org-article:0b521bf3868344fdb2c03dfdeec5ed9f2021-12-02T17:37:10ZA boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts10.1038/s42004-021-00576-12399-3669https://doaj.org/article/0b521bf3868344fdb2c03dfdeec5ed9f2021-09-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00576-1https://doaj.org/toc/2399-3669Frustrated Lewis pairs can be thermally revived from classical Lewis adducts, but the mechanism by which this occurs is not well understood. Here a combined experimental and theoretical study supports a pathway mediated by boron-jumping and dynamic conformational isomerization.Yoichi HoshimotoMahiro SakurabaTakuya KinoshitaMasaki OhboManussada RatanasakJun-ya HasegawaSensuke OgoshiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-6 (2021) |
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DOAJ |
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EN |
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Chemistry QD1-999 |
| spellingShingle |
Chemistry QD1-999 Yoichi Hoshimoto Mahiro Sakuraba Takuya Kinoshita Masaki Ohbo Manussada Ratanasak Jun-ya Hasegawa Sensuke Ogoshi A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| description |
Frustrated Lewis pairs can be thermally revived from classical Lewis adducts, but the mechanism by which this occurs is not well understood. Here a combined experimental and theoretical study supports a pathway mediated by boron-jumping and dynamic conformational isomerization. |
| format |
article |
| author |
Yoichi Hoshimoto Mahiro Sakuraba Takuya Kinoshita Masaki Ohbo Manussada Ratanasak Jun-ya Hasegawa Sensuke Ogoshi |
| author_facet |
Yoichi Hoshimoto Mahiro Sakuraba Takuya Kinoshita Masaki Ohbo Manussada Ratanasak Jun-ya Hasegawa Sensuke Ogoshi |
| author_sort |
Yoichi Hoshimoto |
| title |
A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| title_short |
A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| title_full |
A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| title_fullStr |
A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| title_full_unstemmed |
A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| title_sort |
boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts |
| publisher |
Nature Portfolio |
| publishDate |
2021 |
| url |
https://doaj.org/article/0b521bf3868344fdb2c03dfdeec5ed9f |
| work_keys_str_mv |
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