Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates

The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.

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Autores principales: Seiji Yamazoe, Shinjiro Takano, Wataru Kurashige, Toshihiko Yokoyama, Kiyofumi Nitta, Yuichi Negishi, Tatsuya Tsukuda
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/0df2f791d40547c4b19af8ed61953426
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