Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates

The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.

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Autores principales:	Seiji Yamazoe, Shinjiro Takano, Wataru Kurashige, Toshihiko Yokoyama, Kiyofumi Nitta, Yuichi Negishi, Tatsuya Tsukuda
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/0df2f791d40547c4b19af8ed61953426
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spelling	oai:doaj.org-article:0df2f791d40547c4b19af8ed619534262021-12-02T15:34:08ZHierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates10.1038/ncomms104142041-1723https://doaj.org/article/0df2f791d40547c4b19af8ed619534262016-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms10414https://doaj.org/toc/2041-1723The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.Seiji YamazoeShinjiro TakanoWataru KurashigeToshihiko YokoyamaKiyofumi NittaYuichi NegishiTatsuya TsukudaNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
description	The hierarchy of bond stiffness may contribute to the thermal properties of metal clusters. Here, the authors use X-ray absorption spectroscopy to study the stiffness of the gold–gold and gold–sulfur bonds in a series of thiolate-protected, icosahedral-based gold clusters.
format	article
author	Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda
author_facet	Seiji Yamazoe Shinjiro Takano Wataru Kurashige Toshihiko Yokoyama Kiyofumi Nitta Yuichi Negishi Tatsuya Tsukuda
author_sort	Seiji Yamazoe
title	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_short	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_full	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_fullStr	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_full_unstemmed	Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
title_sort	hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/0df2f791d40547c4b19af8ed61953426
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Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates

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