Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder

Abstract Carcinogenic Sudan I has been added illegally into spices for an apparent freshness. 1H solution and solid-state (SS) nuclear magnetic resonance (NMR) spectroscopies were applied and compared for determination of Sudan I in paprika powders (PPs). For solution NMR, PPs spiked with Sudan I we...

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Autores principales:	Yaxi Hu, Shuo Wang, Shenlin Wang, Xiaonan Lu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/0f160fb4668b43b7a20ac4a8f555b63c
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spelling	oai:doaj.org-article:0f160fb4668b43b7a20ac4a8f555b63c2021-12-02T16:06:39ZApplication of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder10.1038/s41598-017-02921-82045-2322https://doaj.org/article/0f160fb4668b43b7a20ac4a8f555b63c2017-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-02921-8https://doaj.org/toc/2045-2322Abstract Carcinogenic Sudan I has been added illegally into spices for an apparent freshness. 1H solution and solid-state (SS) nuclear magnetic resonance (NMR) spectroscopies were applied and compared for determination of Sudan I in paprika powders (PPs). For solution NMR, PPs spiked with Sudan I were extracted with acetonitrile, centrifuged, rotor-evaporated, and re-dissolved in DMSO-d6 for spectral collection. For SSNMR, Sudan I contaminated PPs were mixed with DMSO-d6 solution and used for spectral collection. Linear regression models constructed for quantitative analyses resulted in the average accuracies for unknown samples as 98% and 105%, respectively. Limits of detection for the solution NMR and SSNMR spectrometers were 6.7 and 128.6 mg kg−1, while the limits of quantification were 22.5 and 313.7 mg kg−1. The overall analysis time required by both methods was similar (35 and 32 min). Both NMR techniques are feasible for rapid and accurate determination of Sudan I adulteration in PPs.Yaxi HuShuo WangShenlin WangXiaonan LuNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Yaxi Hu Shuo Wang Shenlin Wang Xiaonan Lu Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
description	Abstract Carcinogenic Sudan I has been added illegally into spices for an apparent freshness. 1H solution and solid-state (SS) nuclear magnetic resonance (NMR) spectroscopies were applied and compared for determination of Sudan I in paprika powders (PPs). For solution NMR, PPs spiked with Sudan I were extracted with acetonitrile, centrifuged, rotor-evaporated, and re-dissolved in DMSO-d6 for spectral collection. For SSNMR, Sudan I contaminated PPs were mixed with DMSO-d6 solution and used for spectral collection. Linear regression models constructed for quantitative analyses resulted in the average accuracies for unknown samples as 98% and 105%, respectively. Limits of detection for the solution NMR and SSNMR spectrometers were 6.7 and 128.6 mg kg−1, while the limits of quantification were 22.5 and 313.7 mg kg−1. The overall analysis time required by both methods was similar (35 and 32 min). Both NMR techniques are feasible for rapid and accurate determination of Sudan I adulteration in PPs.
format	article
author	Yaxi Hu Shuo Wang Shenlin Wang Xiaonan Lu
author_facet	Yaxi Hu Shuo Wang Shenlin Wang Xiaonan Lu
author_sort	Yaxi Hu
title	Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
title_short	Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
title_full	Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
title_fullStr	Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
title_full_unstemmed	Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder
title_sort	application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of sudan dye i in paprika powder
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/0f160fb4668b43b7a20ac4a8f555b63c
work_keys_str_mv	AT yaxihu applicationofnuclearmagneticresonancespectroscopyinfoodadulterationdeterminationtheexampleofsudandyeiinpaprikapowder AT shuowang applicationofnuclearmagneticresonancespectroscopyinfoodadulterationdeterminationtheexampleofsudandyeiinpaprikapowder AT shenlinwang applicationofnuclearmagneticresonancespectroscopyinfoodadulterationdeterminationtheexampleofsudandyeiinpaprikapowder AT xiaonanlu applicationofnuclearmagneticresonancespectroscopyinfoodadulterationdeterminationtheexampleofsudandyeiinpaprikapowder
_version_	1718384885204254720

Application of nuclear magnetic resonance spectroscopy in food adulteration determination: the example of Sudan dye I in paprika powder

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